Atmospheric pressure aminocarbonylation of aryl iodides using palladium nanoparticles supported on MOF-5

被引:110
作者
Dang, Tuan T. [1 ]
Zhu, Yinghuai [1 ]
Ghosh, Subhash C. [1 ]
Chen, Anqi [1 ]
Chai, Christina L. L. [1 ]
Seayad, Abdul M. [1 ]
机构
[1] ICES, Singapore 138665, Singapore
关键词
METAL-ORGANIC FRAMEWORKS; AMIDE BOND FORMATION; HETEROGENEOUS CATALYSIS; CARBONYLATION; PHYSISORPTION; HALIDES; STORAGE; LIGAND;
D O I
10.1039/c2cc16808a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient amide synthesis by atmospheric pressure aminocarbonylation using palladium nanoparticles supported on MOF-5 is reported. Interestingly, only 0.5 wt% palladium loading was required to achieve high yields. The catalyst is recyclable and offers negligible palladium leaching.
引用
收藏
页码:1805 / 1807
页数:3
相关论文
共 30 条
[21]   Metals@MOFs - Loading MOFs with Metal Nanoparticles for Hybrid Functions [J].
Meilikhov, Mikhail ;
Yusenko, Kiri ;
Esken, Daniel ;
Turner, Stuart ;
Van Tendeloo, Gustaaf ;
Fischer, Roland A. .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (24) :3701-3714
[22]   Amide bond formation and peptide coupling [J].
Montalbetti, CAGN ;
Falque, V .
TETRAHEDRON, 2005, 61 (46) :10827-10852
[23]   Hydrogen physisorption in metal-organic porous crystals [J].
Panella, B ;
Hirscher, M .
ADVANCED MATERIALS, 2005, 17 (05) :538-+
[24]   Asymmetric Nanocatalysis: N-Heterocyclic Carbenes as Chiral Modifiers of Fe3O4/Pd nanoparticles [J].
Ranganath, Kalluri V. S. ;
Kloesges, Johannes ;
Schaefer, Andreas H. ;
Glorius, Frank .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (42) :7786-7789
[25]   Gas adsorption sites in a large-pore metal-organic framework [J].
Rowsell, JLC ;
Spencer, EC ;
Eckert, J ;
Howard, JAK ;
Yaghi, OM .
SCIENCE, 2005, 309 (5739) :1350-1354
[26]   Solution infiltration of palladium into MOF-5: synthesis, physisorption and catalytic properties [J].
Sabo, Michal ;
Henschel, Antje ;
Froede, Heidrun ;
Klemm, Elias ;
Kaskel, Stefan .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (36) :3827-3832
[27]   Microwave-Assisted Carbonylation and Cyclocarbonylation of Aryl Iodides under Ligand Free Heterogeneous Catalysis [J].
Salvadori, Jessica ;
Balducci, Evita ;
Zaza, Silvia ;
Petricci, Elena ;
Taddei, Maurizio .
JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (06) :1841-1847
[28]   PALLADIUM-CATALYZED AMIDATION OF ARYL, HETEROCYCLIC, AND VINYLIC HALIDES [J].
SCHOENBE.A ;
HECK, RF .
JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (23) :3327-3331
[29]   Amide bond formation: beyond the myth of coupling reagents [J].
Valeur, Eric ;
Bradley, Mark .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (02) :606-631
[30]   Ru nanoparticles immobilized on metal-organic framework nanorods by supercritical CO2-methanol solution: highly efficient catalyst [J].
Zhao, Yueju ;
Zhang, Jianling ;
Song, Jinliang ;
Li, Jianshen ;
Liu, Jinli ;
Wu, Tianbin ;
Zhang, Peng ;
Han, Buxing .
GREEN CHEMISTRY, 2011, 13 (08) :2078-2082