Atmospheric pressure aminocarbonylation of aryl iodides using palladium nanoparticles supported on MOF-5

被引:110
作者
Dang, Tuan T. [1 ]
Zhu, Yinghuai [1 ]
Ghosh, Subhash C. [1 ]
Chen, Anqi [1 ]
Chai, Christina L. L. [1 ]
Seayad, Abdul M. [1 ]
机构
[1] ICES, Singapore 138665, Singapore
关键词
METAL-ORGANIC FRAMEWORKS; AMIDE BOND FORMATION; HETEROGENEOUS CATALYSIS; CARBONYLATION; PHYSISORPTION; HALIDES; STORAGE; LIGAND;
D O I
10.1039/c2cc16808a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient amide synthesis by atmospheric pressure aminocarbonylation using palladium nanoparticles supported on MOF-5 is reported. Interestingly, only 0.5 wt% palladium loading was required to achieve high yields. The catalyst is recyclable and offers negligible palladium leaching.
引用
收藏
页码:1805 / 1807
页数:3
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