Atmospheric pressure aminocarbonylation of aryl iodides using palladium nanoparticles supported on MOF-5

被引:110
作者
Dang, Tuan T. [1 ]
Zhu, Yinghuai [1 ]
Ghosh, Subhash C. [1 ]
Chen, Anqi [1 ]
Chai, Christina L. L. [1 ]
Seayad, Abdul M. [1 ]
机构
[1] ICES, Singapore 138665, Singapore
关键词
METAL-ORGANIC FRAMEWORKS; AMIDE BOND FORMATION; HETEROGENEOUS CATALYSIS; CARBONYLATION; PHYSISORPTION; HALIDES; STORAGE; LIGAND;
D O I
10.1039/c2cc16808a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient amide synthesis by atmospheric pressure aminocarbonylation using palladium nanoparticles supported on MOF-5 is reported. Interestingly, only 0.5 wt% palladium loading was required to achieve high yields. The catalyst is recyclable and offers negligible palladium leaching.
引用
收藏
页码:1805 / 1807
页数:3
相关论文
共 30 条
[1]   Metal-catalysed approaches to amide bond formation [J].
Allen, C. Liana ;
Williams, Jonathan M. J. .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (07) :3405-3415
[2]   Palladium-Catalyzed Carbonylation-A Reaction Come of Age [J].
Barnard, Christopher F. J. .
ORGANOMETALLICS, 2008, 27 (21) :5402-5422
[3]   Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds [J].
Brennfuehrer, Anne ;
Neumann, Helfried ;
Beller, Matthias .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (23) :4114-4133
[4]  
BURKARD W, 1980, Patent No. 4210754
[5]   Key green chemistry research areas - a perspective from pharmaceutical manufacturers [J].
Constable, David J. C. ;
Dunn, Peter J. ;
Hayler, John D. ;
Humphrey, Guy R. ;
Leazer, Johnnie L., Jr. ;
Linderman, Russell J. ;
Lorenz, Kurt ;
Manley, Julie ;
Pearlman, Bruce A. ;
Wells, Andrew ;
Zaks, Aleksey ;
Zhang, Tony Y. .
GREEN CHEMISTRY, 2007, 9 (05) :411-420
[6]   Engineering Metal Organic Frameworks for Heterogeneous Catalysis [J].
Corma, A. ;
Garcia, H. ;
Llabres i Xamena, F. X. L. I. .
CHEMICAL REVIEWS, 2010, 110 (08) :4606-4655
[7]   High-efficiency aminocarbonylation by introducing CO to a pressurized continuous flow reactor [J].
Csajagi, Csaba ;
Borcsek, Bernadett ;
Niesz, Krisztian ;
Kovacs, Ildiko ;
Szekelyhidi, Zsolt ;
Bajko, Zoltan ;
Urge, Laszlo ;
Darvas, Ferenc .
ORGANIC LETTERS, 2008, 10 (08) :1589-1592
[8]   Industrial applications of metal-organic frameworks [J].
Czaja, Alexander U. ;
Trukhan, Natalia ;
Mueller, Ulrich .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293
[9]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[10]   Pd@MOF-5: limitations of gas-phase infiltration and solution impregnation of [Zn4O(bdc)3] (MOF-5) with metal-organic palladium precursors for loading with Pd nanoparticles [J].
Esken, Daniel ;
Zhang, Xiaoning ;
Lebedev, Oleg I. ;
Schroeder, Felicitas ;
Fischer, Roland A. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (09) :1314-1319