Low-Frequency Dependence of Conductivity and Dielectric Properties of Polyaniline/ZnFe2O4 Nanocomposites

被引:7
作者
Prasanna, G. D. [1 ]
Jayanna, H. S. [1 ]
Lamani, Ashok R. [1 ]
Dinesha, M. L. [1 ]
Naveen, C. S. [1 ]
Shankaramurthy, G. J. [2 ]
机构
[1] Kuvempu Univ, Dept PG Studies & Res Phys, Shankarghatta 577451, Karnataka, India
[2] Bapuji Inst Engn & Technol, Davangere 577004, Karnataka, India
关键词
COMBUSTION SYNTHESIS; MAGNETIC-PROPERTIES; FERRITE; SPECTROSCOPY; TRANSPORT;
D O I
10.1088/0256-307X/28/11/117701
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Conducting polyaniline/ZnFe2O4 nanocomposites are synthesized by using a simple and inexpensive one-step in-situ polymerization method in the presence of ZnFe2O4 nanoparticles. The structural, morphological and electrical properties of the samples are characterized by x-ray diffraction, Fourier transform infrared spectra and scanning electron microscopy. These results reveal the formation of polyaniline/ZnFe2O4 nanocomposites. The morphology of these samples is studied by scanning electron microscopy. Further, the ac conductivity (sigma(ac)) of these composites is investigated in the frequency range of 1 kHz-10 MHz. The presence of polarons and bipolarons are responsible for the frequency dependence of ac conductivity in these nanocomposites. The ac conductivity is found to be constant up to 1 MHz and thereafter it increases steeply. The ac conductivity of 0.695 S.cm(-1) at room temperature is observed as the maxima for the polyaniline with 40wt% of the ZnFe2O4 nanocomposite.
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页数:4
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共 23 条
[1]   Inhibition of corrosion of steels with the exploitation of conducting polymers [J].
Ahmad, N ;
MacDiarmid, AG .
SYNTHETIC METALS, 1996, 78 (02) :103-110
[2]   Effect of ferrofluid concentration on electrical and magnetic properties of the Fe3O4/PANI nanocomposites [J].
Alam, Javed ;
Riaz, Ufana ;
Ahmad, Sharif .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 314 (02) :93-99
[3]   Characterization and dielectric properties of polyaniline-TiO2 nanocomposites [J].
Dey, A ;
De, S ;
De, A ;
De, SK .
NANOTECHNOLOGY, 2004, 15 (09) :1277-1283
[4]   Microwave properties of EPDM/PAni-DBSA blends [J].
Faez, R ;
Martin, IM ;
de Paoli, MA ;
Rezende, MC .
SYNTHETIC METALS, 2001, 119 (1-3) :435-436
[5]   Magnetic nanoparticles and nanoparticle assemblies from metallorganic precursors [J].
Gun'ko, YK ;
Pillai, SC ;
McInerney, D .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2001, 12 (4-6) :299-302
[6]   Development of a novel combustion synthesis method for synthesizing of ceramic oxide powders [J].
Hwang, CC ;
Wu, TY ;
Wan, J ;
Tsai, JS .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2004, 111 (01) :49-56
[7]   Dielectric spectroscopy of porous HCl-doped polyaniline containing lanthanum ions [J].
Jiang, Jing ;
Ai, Lun-Hong .
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2008, 47 (03) :620-626
[8]   Electrical and magnetic properties of magnesium ferrite ceramics doped with Bi2O3 [J].
Kong, L. B. ;
Li, Z. W. ;
Lin, G. Q. ;
Gan, Y. B. .
ACTA MATERIALIA, 2007, 55 (19) :6561-6572
[9]   Preparation of magnetic and conductive NiZn ferrite-polyaniline nanocomposites with core-shell structure [J].
Li, GJ ;
Yan, SF ;
Zhou, EL ;
Chen, YM .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 276 (1-3) :40-44
[10]   Frequency-dependent conductivity and dielectric permittivity of polyaniline/TiO2 composites [J].
Manjunath, S. ;
Anilkumar, Koppalkar R. ;
Revanasiddappa, M. ;
Prasad, M. V. N. Ambika .
FERROELECTRICS LETTERS SECTION, 2008, 35 (1-2) :36-46