Low-Frequency Dependence of Conductivity and Dielectric Properties of Polyaniline/ZnFe2O4 Nanocomposites

被引:7
作者
Prasanna, G. D. [1 ]
Jayanna, H. S. [1 ]
Lamani, Ashok R. [1 ]
Dinesha, M. L. [1 ]
Naveen, C. S. [1 ]
Shankaramurthy, G. J. [2 ]
机构
[1] Kuvempu Univ, Dept PG Studies & Res Phys, Shankarghatta 577451, Karnataka, India
[2] Bapuji Inst Engn & Technol, Davangere 577004, Karnataka, India
关键词
COMBUSTION SYNTHESIS; MAGNETIC-PROPERTIES; FERRITE; SPECTROSCOPY; TRANSPORT;
D O I
10.1088/0256-307X/28/11/117701
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Conducting polyaniline/ZnFe2O4 nanocomposites are synthesized by using a simple and inexpensive one-step in-situ polymerization method in the presence of ZnFe2O4 nanoparticles. The structural, morphological and electrical properties of the samples are characterized by x-ray diffraction, Fourier transform infrared spectra and scanning electron microscopy. These results reveal the formation of polyaniline/ZnFe2O4 nanocomposites. The morphology of these samples is studied by scanning electron microscopy. Further, the ac conductivity (sigma(ac)) of these composites is investigated in the frequency range of 1 kHz-10 MHz. The presence of polarons and bipolarons are responsible for the frequency dependence of ac conductivity in these nanocomposites. The ac conductivity is found to be constant up to 1 MHz and thereafter it increases steeply. The ac conductivity of 0.695 S.cm(-1) at room temperature is observed as the maxima for the polyaniline with 40wt% of the ZnFe2O4 nanocomposite.
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页数:4
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