A novel separator material consisting of Zeoliticlmidazolate Framework-4 (ZIF-4) and its electrochemical performance for lithium-ions battery

被引：32
作者：
Dai, Meng [1 ]
Shen, Jianxing [1 ]
Zhang, Jiayan [2 ]
Li, Guangda [1 ]
机构：
[1] Qilu Univ Technol, Key Lab Proc & Testing Technol Glass & Funct Cera, Jinan 250353, Shandong, Peoples R China
[2] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Hubei, Peoples R China
来源：
JOURNAL OF POWER SOURCES | 2017年 / 369卷
基金：
中国国家自然科学基金;
关键词：
ZIF-4; separator; PP separator; Blade-coating; Lithium-ions battery; GEL; MEMBRANE; ELECTROLYTE;
D O I：
10.1016/j.jpowsour.2017.09.058
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel film based on zeoliticimidazolate framework-4 (ZIF-4) as a separator is prepared by hydro thermal method and a stable electrode-supported separator is synthesized by blade-coating technology. The ZIF-4 separator with the thicknesses of about 60 pm is coated on Li[Ni1/3Co1/3Mn1/3]O-2 electrode with a slurry of ZIF-4, PVDF and amount of N-methyl-2-pyrrolidone (NMP). It is found that the ZIF-4 separator has good thermal stability and cycle performance than conventional polypropylene (PP) separator. And it has larger liquid electrolyte uptake, higher retention, higher ionic conductivity and lower interfacial resistance. The C-rate performance of ZIF-4 separator is superior than PP separator, and it enhances the safety of lithium-ions battery. Therefore, the ZIF-4 separator is a promising material to improve stability and safety of lithium-ions battery. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：27 / 34
页数：8
相关论文
共 28 条
[1]   A comparison of the amorphization of zeolitic imidazolate frameworks (ZIFs) and aluminosilicate zeolites by ball-milling [J].
Baxter, Emma F. ;
Bennett, Thomas D. ;
Cairns, Andrew B. ;
Brownbill, Nick J. ;
Goodwin, Andrew L. ;
Keen, David A. ;
Chater, Philip A. ;
Blancc, Frederic ;
Cheetham, Anthony K. .
DALTON TRANSACTIONS, 2016, 45 (10) :4258-4268
[2]   Facile Mechanosynthesis of Amorphous Zeolitic Imidazolate Frameworks [J].
Bennett, Thomas D. ;
Cao, Shuai ;
Tan, Jin Chong ;
Keen, David A. ;
Bithell, Erica G. ;
Beldon, Patrick J. ;
Friscic, Tomislav ;
Cheetham, Anthony K. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (37) :14546-14549
[3]   Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4) [J].
Bennett, Thomas D. ;
Simoncic, Petra ;
Moggach, Stephen A. ;
Gozzo, Fabia ;
Macchi, Piero ;
Keen, David A. ;
Tan, Jin-Chong ;
Cheetham, Anthony K. .
CHEMICAL COMMUNICATIONS, 2011, 47 (28) :7983-7985
[4]   Porous SiO2 as a separator to improve the electrochemical performance of spinel LiMn2O4 cathode [J].
Chen, Jingjuan ;
Wang, Suqing ;
Cai, Dandan ;
Wang, Haihui .
JOURNAL OF MEMBRANE SCIENCE, 2014, 449 :169-175
[5]   Electrical Energy Storage for the Grid: A Battery of Choices [J].
Dunn, Bruce ;
Kamath, Haresh ;
Tarascon, Jean-Marie .
SCIENCE, 2011, 334 (6058) :928-935
[6]   Challenges in the development of advanced Li-ion batteries: a review [J].
Etacheri, Vinodkumar ;
Marom, Rotem ;
Elazari, Ran ;
Salitra, Gregory ;
Aurbach, Doron .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3243-3262
[7]   Adsorptive Separation of Olefin/Paraffin Mixtures with ZIF-4 [J].
Hartmann, Martin ;
Boehme, Ulrike ;
Hovestadt, Maximilian ;
Paula, Carolin .
LANGMUIR, 2015, 31 (45) :12382-12389
[8]   Pure Inorganic Separator for Lithium Ion Batteries [J].
He, Meinan ;
Zhang, Xinjie ;
Jiang, Kuiyang ;
Wang, Joe ;
Wang, Yan .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (01) :738-742
[9]   Effect of phase inversion on microporous structure development of Al2O3/poly(vinylidene fluoride-hexafluoropropylene)-based ceramic composite separators for lithium-ion batteries [J].
Jeong, Hyun-Seok ;
Kim, Dong-Won ;
Jeong, Yeon Uk ;
Lee, Sang-Young .
JOURNAL OF POWER SOURCES, 2010, 195 (18) :6116-6121
[10]   A high-rate long-life Li4Ti5O12/Li[Ni0.45Co0.1Mn1.45]O4 lithium-ion battery [J].
Jung, Hun-Gi ;
Jang, Min Woo ;
Hassoun, Jusef ;
Sun, Yang-Kook ;
Scrosati, Bruno .
NATURE COMMUNICATIONS, 2011, 2
123