An n-Channel Two-Dimensional Covalent Organic Framework

被引：325

作者：

Ding, Xuesong ^{[2
]}

Chen, Long ^{[2
]}

Honsho, Yoshihito ^{[1
]}

Feng, Xiao ^{[2
]}

Saenpawang, Oraphan ^{[3
,4
]}

Guo, Jingdong ^{[5
]}

Saeki, Akinori ^{[1
]}

Seki, Shu ^{[1
]}

Irle, Stephan ^{[3
]}

Nagase, Shigeru ^{[5
]}

Parasuk, Vudhichai ^{[4
]}

Jiang, Donglin ^{[2
,6
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Natl Inst Nat Sci, Inst Mol Sci, Dept Mat Mol Sci, Okazaki, Aichi 4448787, Japan

[3] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648601, Japan

[4] Chulalongkorn Univ, Computat Chem Unit Cell, Dept Chem, Bangkok 10330, Thailand

[5] Natl Inst Nat Sci, Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan

[6] Japan Sci & Technol Agcy, PRESTO, Chiyoda Ku, Tokyo 1020075, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 37期

关键词：

TRIAZINE-BASED FRAMEWORKS; RETICULAR SYNTHESIS; CRYSTALLINE; HYDROGEN; STORAGE;

D O I：

10.1021/ja2052396

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Co-condensation of metallophthalocyanine with an electron-deficient benzothiadiazole (BTDA) block leads to the formation of a two-dimensional covalent organic framework (2D-NiPc-BTDA COF) that assumes a belt shape and consists of AA stacking of 2D polymer sheets. Integration of BTDA blocks at the edges of a tetragonal metallophthalocyanine COF causes drastic changes in the carrier-transport mode and a switch from a hole-transporting skeleton to an electron-transporting framework 2D-NiPc-BTDA COF exhibits broad and enhanced absorbance up to 1000 nm, shows panchromatic photoconductivity, is highly sensitive to near-infrared photons, and has excellent electron mobility as high as 0.6 cm(2)V(-1)S(-1).

引用

页码：14510 / 14513

页数：4

共 26 条

[1] Rational Extension of the Family of Layered, Covalent, Triazine-Based Frameworks with Regular Porosity [J].

Bojdys, Michael J. ;

Jeromenok, Jekaterina ;

Thomas, Arne ;

Antonietti, Markus .

ADVANCED MATERIALS, 2010, 22 (19) :2202-+

[2] Rapid Microwave Synthesis and Purification of Porous Covalent Organic Frameworks [J].

Campbell, Neil L. ;

Clowes, Rob ;

Ritchie, Lyndsey K. ;

Cooper, Andrew I. .

CHEMISTRY OF MATERIALS, 2009, 21 (02) :204-206

[3] Oriented 2D Covalent Organic Framework Thin Films on Single-Layer Graphene [J].

Colson, John W. ;

Woll, Arthur R. ;

Mukherjee, Arnab ;

Levendorf, Mark P. ;

Spitler, Eric L. ;

Shields, Virgil B. ;

Spencer, Michael G. ;

Park, Jiwoong ;

Dichtel, William R. .

SCIENCE, 2011, 332 (6026) :228-231

[4] Reticular synthesis of microporous and mesoporous 2D covalent organic frameworks [J].

Cote, Adrien P. ;

El-Kaderi, Hani M. ;

Furukawa, Hiroyasu ;

Hunt, Joseph R. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (43) :12914-+

[5] Porous, crystalline, covalent organic frameworks [J].

Côté, AP ;

Benin, AI ;

Ockwig, NW ;

O'Keeffe, M ;

Matzger, AJ ;

Yaghi, OM .

SCIENCE, 2005, 310 (5751) :1166-1170

[6] Synthesis of Metallophthalocyanine Covalent Organic Frameworks That Exhibit High Carrier Mobility and Photoconductivity [J].

Ding, Xuesong ;

Guo, Jia ;

Feng, Xiao ;

Honsho, Yoshihito ;

Guo, Jingdong ;

Seki, Shu ;

Maitarad, Phornphimon ;

Saeki, Akinori ;

Nagase, Shigeru ;

Jiang, Donglin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (06) :1289-1293

[7] A Covalent Organic Framework with 4 nm open pores [J].

Dogru, Mirjam ;

Sonnauer, Andreas ;

Gavryushin, Andrei ;

Knochel, Paul ;

Bein, Thomas .

CHEMICAL COMMUNICATIONS, 2011, 47 (06) :1707-1709

[8]

Doonan CJ, 2010, NAT CHEM, V2, P235, DOI [10.1038/nchem.548, 10.1038/NCHEM.548]

[9] Designed synthesis of 3D covalent organic frameworks [J].

El-Kaderi, Hani M. ;

Hunt, Joseph R. ;

Mendoza-Cortes, Jose L. ;

Cote, Adrien P. ;

Taylor, Robert E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2007, 316 (5822) :268-272

[10] Synthesis, Properties, and Gas Separation Studies of a Robust Diimide-Based Microporous Organic Polymer [J].

Farha, Omar K. ;

Spokoyny, Alexander M. ;

Hauser, Brad G. ;

Bae, Youn-Sang ;

Brown, Samantha E. ;

Snurr, Randall Q. ;

Mirkin, Chad A. ;

Hupp, Joseph T. .

CHEMISTRY OF MATERIALS, 2009, 21 (14) :3033-3035

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