Catalytic oxidation of methane at low temperature over Pd-containing perovskite type oxides

被引：6
作者：
Wu, Yuehui [1 ,2 ]
Lu, Laitao [2 ]
机构：
[1] Nanchang Hangkong Univ, Dept Chem Mat, Nanchang 330063, Peoples R China
[2] Nanchang Univ, Inst Appl Chem, Nanchang 330069, Peoples R China
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2008年 / 93卷 / 02期
关键词：
palladium-substituted; supported; perovskite-type oxide; catalytic oxidation;
D O I：
10.1007/s11144-008-5244-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two types of catalysts with the same palladium loading, palladium-substituted perovskite La0.95Ce0.05Co0.95Pd0.05O3 and perovskite-supported palladium catalyst Pd/La0.95Ce0.05CoO3 were prepared by the combustion and impregnation method, respectively. The catalyst structure was characterized by X-ray diffraction (XRD), BET measurements, temperature-programmed reduction (TPR) and the methane oxidation activity of the catalysts were investigated in detail. It was found that the activity performance of Pd/La0.95Ce0.05CoO3 was higher than that of La0.95Ce0.05Co0.95Pd0.05O3, and this was owing to the ease of reduction of palladium in the former.
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收藏
页码：305 / 313
页数：9
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