Allylic alkylation and ring-closing metathesis in sequence: A successful cohabitation of Pd and Ru

被引：46

作者：

Kammerer, Claire ^{[1
]}

Prestat, Guillaume ^{[1
]}

Gaillard, Thomas ^{[1
]}

Madec, David ^{[1
]}

Poli, Giovanni ^{[1
]}

机构：

[1] Univ Paris 06, UMR CNRS 7611, Chim Organ Lab, Inst Chim Mol FR2769, F-75005 Paris, France

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 03期

关键词：

D O I：

10.1021/ol702694v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An allylic alkylation/ring-closing metathesis domino catalytic process, wherein a palladium and a ruthenium catalyst are concomitantly present in the reaction mixture from the outset of the reaction, is developed. Evidence for Grubbs' catalysts activity in allylic alkylation is also reported.

引用

页码：405 / 408

页数：4

共 31 条

[1] Non-metathetic behavior patterns of Grubbs' carbene
Alcaide, B
Almendros, P
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (06) : 1259 - 1262
[2] Synthesis of branched polyolefins using a combination of homogeneous metallocene mimics
Barnhart, RW
Bazan, GC
Mourey, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (05) : 1082 - 1083
[3] 4-aryl-2-quinolones through a pseudo-domino Heck/Buchwald-Hartwig reaction in a molten tetrabutylammonium acetate/tetrabutylammonium bromide mixture
Battistuzzi, Gianfranco
Bernini, Roberta
Cacchi, Sandro
De Salve, Ilse
Fabrizi, Giancarlo
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (03) : 297 - 302
[4] In situ tandem allylic acetate isomerisation-ring closing metathesis: 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ruthenium benzylidenes and palladium(0)-phosphine combinations
Braddock, DC
Matsuno, A
[J]. TETRAHEDRON LETTERS, 2002, 43 (18) : 3305 - 3308
[5] On the use of tandem allylic acetate isomerisation and ring-closing metathesis with palladium(0) phosphine complexes and ruthenium benzylidenes as orthogonal catalysts
Braddock, DC
Wildsmith, AJ
[J]. TETRAHEDRON LETTERS, 2001, 42 (18) : 3239 - 3242
[6] One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence
Comins, Daniel L.
Dinsmore, Jason M.
Marks, Lucas R.
[J]. CHEMICAL COMMUNICATIONS, 2007, (40) : 4170 - 4171
[7] Tandem cross-metathesis/hydrogenation/cyclization reactions by using compatible catalysts
Cossy, J
Bargiggia, F
BouzBouz, S
[J]. ORGANIC LETTERS, 2003, 5 (04) : 459 - 462
[8] Regio- and diastereoselective tandem rhodium-catalyzed allylic alkylation Pauson-Khand annulation reactions
Evans, PA
Robinson, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (19) : 4609 - 4610
[9] Tandem catalysis: a taxonomy and illustrative review
Fogg, DE
dos Santos, EN
[J]. COORDINATION CHEMISTRY REVIEWS, 2004, 248 (21-24) : 2365 - 2379
[10] Sequential and cascade olefin metathesis - Intramolecular Heck reaction.
Grigg, R
Sridharan, V
York, M
[J]. TETRAHEDRON LETTERS, 1998, 39 (23) : 4139 - 4142

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