Novel 3D Wollastonite-Based Scaffolds from Preceramic Polymers Containing Micro- and Nano-Sized Reactive Particles

被引:34
作者
Bernardo, Enrico [1 ]
Colombo, Paolo [1 ,2 ]
Dainese, Emil [1 ]
Lucchetta, Giovanni [1 ]
Bariani, Paolo F. [1 ]
机构
[1] Univ Padua, Dipartimento Ingn Meccan, I-35131 Padua, Italy
[2] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
关键词
CERAMICS;
D O I
10.1002/adem.201100241
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Wollastonite (CaSiO3) ceramics are well known biomaterials which can be produced using many different techniques. The present paper illustrates an innovative processing method employing preceramic polymers (silicone resins) containing CaCO3 micro- and nano-sized particles, which act as reactive fillers. Silica from the decomposition of the silicone resins reacts at low temperature with the CaO deriving from the fillers, yielding wollastonite ceramics. Hydroxyapatite powders can also be added, to modify the biological response of the material. This approach enables the fabrication of 3D scaffolds via fused deposition or via conventional hot extrusion.
引用
收藏
页码:269 / 274
页数:6
相关论文
共 17 条
[1]   Novel mullite synthesis based on alumina nanoparticles and a preceramic polymer [J].
Bernardo, E ;
Colombo, P ;
Pippel, E ;
Woltersdorf, J .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (05) :1577-1583
[2]   Development of multiphase bioceramics from a filler-containing preceramic polymer [J].
Bernardo, E. ;
Tomasella, E. ;
Colombo, P. .
CERAMICS INTERNATIONAL, 2009, 35 (04) :1415-1421
[3]   Porous wollastonite hydroxyapatite bioceramics from a preceramic polymer and micro- or nano-sized fillers [J].
Bernardo, Enrico ;
Colombo, Paolo ;
Cacciotti, Ilaria ;
Bianco, Alessandra ;
Bedini, Rossella ;
Pecci, Raffaella ;
Pardun, Karoline ;
Treccani, Laura ;
Rezwan, Kurosch .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2012, 32 (02) :399-408
[4]   Polymer-Derived Ceramics: 40 Years of Research and Innovation in Advanced Ceramics [J].
Colombo, Paolo ;
Mera, Gabriela ;
Riedel, Ralf ;
Soraru, Gian Domenico .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2010, 93 (07) :1805-1837
[5]  
Cromme P, 2002, ADV ENG MATER, V4, P873, DOI 10.1002/1527-2648(20021105)4:11<873::AID-ADEM873>3.0.CO
[6]  
2-G
[7]   BIOACTIVITY OF WOLLASTONITE CERAMICS - IN-VITRO EVALUATION [J].
DEAZA, PN ;
GUITIAN, F ;
DEAZA, S .
SCRIPTA METALLURGICA ET MATERIALIA, 1994, 31 (08) :1001-1005
[8]   Morphological studies of pseudowollastonite for biomedical application [J].
DeAza, PN ;
Luklinska, ZB ;
Anseau, M ;
Guitian, F ;
DeAza, S .
JOURNAL OF MICROSCOPY, 1996, 182 :24-31
[9]  
Greil P, 2000, ADV ENG MATER, V2, P339, DOI 10.1002/1527-2648(200006)2:6<339::AID-ADEM339>3.0.CO
[10]  
2-K