Black Diatom Colloids toward Efficient Photothermal Converters for Solar-to-Steam Generation

被引:28
作者
Bae, Kihyeon [1 ]
Ku, Bon Jun [2 ]
Kim, Youngjin [1 ]
Mnoyan, Anush [2 ]
Lee, Kyubock [2 ]
Lee, Kyung Jin [1 ]
机构
[1] Chungnam Natl Univ, Dept Chem Engn & Appl Chem, Coll Engn, 99 Daehak Ro St, Daejeon 34134, South Korea
[2] Chungnam Natl Univ, Grad Sch Energy Sci & Technol, 99 Daehak Ro St, Daejeon 34134, South Korea
基金
新加坡国家研究基金会;
关键词
solar-to-steam generation; diatom; chemical vapor deposition; surface treatment; broadband absorption; VAPOR GENERATION; POLYPYRROLE; NANOPARTICLES; GRAPHENE; CONVERSION; MEMBRANES; POLYMERIZATION; DEPOSITION; FILM;
D O I
10.1021/acsami.8b16847
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Steam generation from solar power using converters has attracted significant research attention in recent years as an alternative form of energy conversion from solar energy. Rationally designed photothermal converters are essential to increase the efficiency of steam generation. Here, we propose a novel colloidal type of photothermal converter based on a frustule skeleton, which is a naturally designed colloid containing through-pore structures. Several coating processes were used to provide broadband absorption, magnetic, and water floating properties without deteriorating pore structures, through vapor deposition polymerization of polypyrrole, weak base treatment, and additional vapor deposition polymerization of polystyrene. The prepared colloidal photothermal converter showed superior efficiency for steam generation under sunlight irradiation.
引用
收藏
页码:4531 / 4540
页数:10
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