Electrochemical lithium storage performance of ternary Zn-Co-Ni alloy thin film as negative electrodes by electrodeposition method

Ternary Zn-Co-Ni alloy film electrode as an anode has been investigated, for the first time, for the purpose of electrochemical lithium storage in lithium-ion batteries. In this study, the ternary Zn-Co-Ni alloy film electrode is prepared by electroplating method. The electrodes were examined using X-ray diffraction (XRD), FE-SEM with EDX, and impedance studies. The electrochemical results demonstrate that the Zn-Co-Ni alloy film electrode delivers an initial discharge capacity of 281 mAh g(-1) and improves to 650 mAh g(-1) at the end of 30th cycling with no capacity fading at 0.1 C rate. The charge-discharge properties of the Zn-Co-Ni alloy film electrode are as follows: insertion capacity of 650 mAh g(-1) and delithiation capacity of 512 mAh g(-1) in the 30th cycling, coulombic efficiency of about 80.0% and good cycling behavior. The results suggest that the ternary Zn-Co-Ni alloy thin film electrode obtained via electroplating shows a good candidate anode material for lithium-ion batteries. Crown Copyright (C) 2011 Published by Elsevier B. V. All rights reserved.