A 1D thiocyanato bridge nickel(II) system: crystal structure and magnetic property

被引：36

作者：

Maji, TK

Laskar, IR

Mostafa, G

Welch, AJ

Mukherjee, PS

Chaudhuri, NR ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, W Bengal, India

[2] Ananda Mohan Coll, Kolkata 700009, W Bengal, India

[3] Krishnath Coll, Dept Phys, Berhampur 742101, Orissa, India

[4] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

POLYHEDRON | 2001年 / 20卷 / 7-8期

关键词：

crystal structures; magnetic properties; nickel(II) complexes; thiocyanato bridge complexes; 1D polymer;

D O I：

10.1016/S0277-5387(01)00729-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A one-dimensional coordination polymer of nickel(II), [(mu (N,S)-NCS)(2){Ni(ampy)}](n) (ampy = 1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300-18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J = 1.4 cm(-1) and g = 2.08. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：651 / 655

页数：5

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