Aqua[1-(4-carboxyphenyl)-1H-imidazole-κN3](pyridine-2,6-dicarboxylato-κ3 O2, N, O6)copper(II) monohydrate

被引:1
|
作者
Kong, Fanzhen [1 ]
Yu, Zhangyu [1 ]
机构
[1] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 330031, Shandong, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
CRYSTAL-STRUCTURE;
D O I
10.1107/S1600536811015522
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Cu(C7H3NO4)(C10H8N2O2)(H2O)]center dot H2O, the CuII ion is in a slightly distorted square-pyramidal geometry. Two carboxylate O atoms and one pyridine N atom from a pyridine-2,6-dicarboxylate ligand chelate the CuII ion, forming two stable five-membered metalla rings. One imidazole N atom from a 1-(4-carboxyphenyl)imidazole ligand and one water molecule complete the five-coordination. O-H...O hydrogen bonds involving the coordinated water molecules and carboxylate groups link the complex molecules into chain-containing dinuclear macrocycles. O-H...O hydrogen bonds involving the uncoordinated water molecules link the chains into a layer extending parallel to
引用
收藏
页码:M783 / U1317
页数:11
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