Percolation Transition in Carbon Composite on the Basis of Fullerenes and Exfoliated Graphite

被引:5
作者
Berezkin, V. I. [1 ]
Popov, V. V. [2 ]
机构
[1] Russian Acad Sci, Res Ctr Ecol Safety, St Petersburg, Russia
[2] Russian Acad Sci, Ioffe Inst, St Petersburg, Russia
关键词
D O I
10.1134/S1063783418010043
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The electrical conductivity of a carbon composite on the basis of C-60 fullerenes and exfoliated graphite is investigated in the range of relative contents of components from 0 to 100%. The samples are obtained by the thermal treatment of the initial dispersed mixtures in vacuum in the diffusion-adsorption process and their further cold pressing. The resistivity of the samples gradually increases with an increase in the fraction of fullerenes, and a sharp transition from the conductive state to the dielectric one is observed after achieving certain concentrations of C-60. The interpretation of the results within the percolation theory makes it possible to evaluate the percolation threshold (expressed as a relative content of graphite) as equal to 4.45 wt % and the critical conductivity index as equal to 1.85 (which is typical for three-dimensional two-component disordered media including those having pores).
引用
收藏
页码:207 / 211
页数:5
相关论文
共 17 条
[1]   Preparation, electrical and thermal properties of new exfoliated graphite-based composites [J].
Afanasov, I. M. ;
Morozov, V. A. ;
Kepman, A. V. ;
Ionov, S. G. ;
Seleznev, A. N. ;
Van Tendeloo, G. ;
Audeev, V. V. .
CARBON, 2009, 47 (01) :263-270
[2]   Electrical and galvanomagnetic effects in new sodium-doped fullerene composites [J].
Berezkin, V. I. ;
Popov, V. V. .
PHYSICS OF THE SOLID STATE, 2007, 49 (09) :1803-1810
[3]   New composite materials based on fullerenes [J].
Berezkin, V. I. .
JETP LETTERS, 2006, 83 (09) :388-393
[4]   Charge Transfer in Carbon Composites Based on Fullerenes and Exfoliated Graphite [J].
Berezkin, V. I. .
PHYSICS OF THE SOLID STATE, 2017, 59 (07) :1460-1467
[5]   Carbon Composite Based on Fullerenes and Exfoliated Graphite [J].
Berezkin, V. I. ;
Popov, V. V. ;
Tomkovich, M. V. .
PHYSICS OF THE SOLID STATE, 2017, 59 (03) :620-628
[6]  
Berezkin V. I., 2013, Carbon. Closed Nanoparticles, Macrostructures
[7]  
Berezkin V. I., 2013, INTRO PHYS ADSORPTIO
[8]   Magnetic properties of fullerene superconductors [J].
Buntar, V ;
Weber, HW .
SUPERCONDUCTOR SCIENCE & TECHNOLOGY, 1996, 9 (08) :599-615
[9]   Effect of temperature on the electrical properties of copolymer/carbon black mixtures [J].
El Hasnaoui, M. ;
Graca, M. P. F. ;
Achour, M. E. ;
Costa, L. C. ;
Outzourhit, A. ;
Oueriagli, A. ;
El Harfi, A. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2010, 356 (31-32) :1536-1541
[10]   Electrical characteristics of carbon nanotube-doped composites [J].
Eletskii, A. V. ;
Knizhnik, A. A. ;
Potapkin, B. V. ;
Kenny, J. M. .
PHYSICS-USPEKHI, 2015, 58 (03) :209-251