A novel tandem cyclization of 2,7- or 2,8-bis-unsaturated esters mediated by (eta(2)-propene)TiX(2) (X=Cl or O-i-Pr). A facile construction of bicyclo[3.3.0]octane, -[4.3.0]nonane, and -[3.1.0]hexane skeletons

被引：53

作者：

Suzuki, K ^{[1
]}

Urabe, H ^{[1
]}

Sato, F ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT BIOMOL ENGN,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 36期

关键词：

D O I：

10.1021/ja961928n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：8729 / 8730

页数：2

共 39 条

[1] HIGHLY STEREOCONTROLLED AND REGIOCONTROLLED CYCLOPENTANNULATION VIA ALLYLPHOSPHONATE CONJUGATE ADDITION AND HYDROBORATION OXIDATION ELIMINATION - SYNTHESIS OF PENTALENIC ACID WITH VIRTUALLY COMPLETE STEREOCONTROL AND REGIOCONTROL [J].

AGNEL, G ;

NEGISHI, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) :7424-7426

[2] CHEMOSELECTIVE FUNCTIONALIZATION OF ZIRCONACYCLOPENTENES [J].

AOYAGI, K ;

KASAI, K ;

KONDAKOV, DY ;

HARA, R ;

SUZUKI, N ;

TAKAHASHI, T .

INORGANICA CHIMICA ACTA, 1994, 220 (1-2) :319-326

[3] ZIRCONIUM-PROMOTED INTRAMOLECULAR CYCLIZATION OF TERMINAL ALKYNES AND UNUSUAL CARBONYLATION REACTION [J].

BARLUENGA, J ;

SANZ, R ;

FANANAS, FJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (10) :1009-1010

[4] DEVELOPMENT OF A TITANOCENE-CATALYZED ENYNE CYCLIZATION ISOCYANIDE INSERTION REACTION [J].

BERK, SC ;

GROSSMAN, RB ;

BUCHWALD, SL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (19) :8593-8601

[5] GROUP-4 METAL-COMPLEXES OF BENZYNES, CYCLOALKYNES, ACYCLIC ALKYNES, AND ALKENES [J].

BUCHWALD, SL ;

NIELSEN, RB .

CHEMICAL REVIEWS, 1988, 88 (07) :1047-1058

[6] THE METHYLENATION OF ENOLIZABLE KETONES AND ESTERS USING ORGANOTITANIUM CHEMISTRY [J].

CLAWSON, L ;

BUCHWALD, SL ;

GRUBBS, RH .

TETRAHEDRON LETTERS, 1984, 25 (50) :5733-5736

[7] CATALYTIC DIASTEREOSELECTIVE SYNTHESIS OF CIS-1,2-DISUBSTITUTED CYCLOPROPANOLS FROM ESTERS USING A VICINAL DICARBANION EQUIVALENT [J].

COREY, EJ ;

RAO, SA ;

NOE, MC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) :9345-9346

[8] SYNTHESIS AND CHARACTERIZATION OF LONG-CHAIN ALKYLIDENE-BRIDGED HETERO BIMETALLIC COMPLEXES [J].

HARTNER, FW ;

SCHWARTZ, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (16) :4979-4981

[9] Synthesis of cyclopropylpyrrolidines via reaction of N-allyl-N-propargylamides with a molybdenum carbene complex. Effect of substituents and reaction conditions [J].

Harvey, DF ;

Sigano, DM .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (07) :2268-2272

[10] NEW, EFFICIENT METHOD FOR THE SYNTHESIS OF ALLYLTITANIUM COMPOUNDS FROM ALLYL HALIDES OR ALLYL ALCOHOL DERIVATIVES VIA OXIDATIVE ADDITION - A HIGHLY EFFICIENT AND PRACTICAL SYNTHESIS OF HOMOALLYL ALCOHOLS [J].

KASATKIN, A ;

NAKAGAWA, T ;

OKAMOTO, S ;

SATO, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (13) :3881-3882

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