Study on the physical and chemical composition of agro wastes for the production of 5-hydroxymethylfurfural

被引:18
|
作者
Shamsul, N. S. [1 ]
Kamarudin, S. K. [1 ,2 ]
Rahman, N. A. [1 ]
机构
[1] Univ Kebangsaan Malaysia, Fac Engn & Built Environm, Dept Chem & Proc, Ukm Bangi 43600, Selangor, Malaysia
[2] Univ Kebangsaan Malaysia, Fuel Cell Inst, Ukm Bangi 43600, Selangor, Malaysia
关键词
Co-hydrothermal treatment; Agro wastes; 5-Hydroxymethylfurfural; Carboxylic acid; Extraction; HYDROTHERMAL CARBONIZATION; LIGNOCELLULOSIC BIOMASS; SEWAGE-SLUDGE; BIOFUEL PRODUCTION; RENEWABLE ENERGY; SOLID BIOFUEL; BIO-OIL; CONVERSION; LIQUEFACTION; ACID;
D O I
10.1016/j.biortech.2017.09.140
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Treated sludge, goat manure, sugarcane bagasse, empty fruit bunches of oil palm (EFBP) and dry leaves are agro wastes that have high potential for use as feedstocks for the production of 5-hydroxymethylfurfural (5-HMF). The focus of this study is to investigate the production of 5-HMF from agro wastes via co-hydrothermal (CHT) treatment and extraction. Present study include examine on agro waste's physical and chemical properties and also their thermal degradation behaviour. The analysis of the bio-oil products is conducted by FTIR and GC-MS. Co-hydrothermal experiments were conducted at a temperature of 300 degrees C with an experimental time of 15 min, followed by alcohol extraction. Highest carbon and hydrogen content are 45.94% and 6.49% (dry leaves) with maximum high heating value 18.39 MJ/kg (dry leaves) and fix carbon value 6.60 (goat manure). Through CHT about 39% 5-HMF, 22.97% carboxylic acids, 0.97% of aromatic and 0.73% aldehyde obtained.
引用
收藏
页码:821 / 828
页数:8
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