Solvothermal growth of a ruthenium metal-organic framework featuring HKUST-1 structure type as thin films on oxide surfaces

被引:110
作者
Kozachuk, Olesia
Yusenko, Kirill
Noei, Heshmat [1 ]
Wang, Yuemin [1 ]
Walleck, Stephan [2 ]
Glaser, Thorsten [2 ]
Fischer, Roland A. [1 ]
机构
[1] Ruhr Univ Bochum, Lab Ind Chem, D-44801 Bochum, Germany
[2] Univ Bielefeld, Fac Chem, D-33615 Bielefeld, Germany
关键词
GAS-OCCLUSION PROPERTIES; MONOLAYERS; OXIDATION; ALUMINA; LAYER;
D O I
10.1039/c1cc11107h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Phase-pure crystalline thin films of a mixed-valence Ru-2(II,III) metal-organic framework with 1,3,5-benzenetricarboxylate (btc) as a linker were solvothermally grown on amorphous alumina and silica surfaces. Based on the Rietveld refinement, the structure of Ru-MOF was assigned to be analogous to [Cu-3(btc)(2)] (HKUST-1).
引用
收藏
页码:8509 / 8511
页数:3
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