Statistical mechanics of hydrogen in fcc solid solutions

被引：4

作者：

McLellan, RB ^{[1
]}

Zang, DH ^{[1
]}

机构：

[1] William Marsh Rice Univ, Dept Mech Engn & Mat Sci, Houston, TX 77005 USA

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1999年 / 60卷 / 03期

关键词：

thermodynamic properties; kinetics;

D O I：

10.1016/S0022-3697(98)00288-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A statistical mechanical calculation of the thermodynamic properties of Ni-H solid solutions, based upon the concept of H-atoms possessing translational mobility over path lengths of several lattice parameters, has been shown to be compatible with the observed solubility behavior, but not compatible with the well-established linear Arrhenius behavior of the H-diffusivity above 300 K. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：347 / 351

页数：5

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