Synthesis and the crystal structure of a supramolecular adduct of the [Mo3O4(H2O)6Cl3]+ cluster complex with macrocyclic cavitand cucurbituril

被引：9
作者：
Samsonenko, DG
Virovets, AV
Sharonova, AA
Fedin, VP
Fenske, D
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian branch, Novosibirsk 630090, Russia
[2] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
来源：
RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 03期
关键词：
cluster complexes; aqua complexes; molybdenum; cucurbituril; supramolecular compound; crystal structure; X-ray diffraction analysis;
D O I：
10.1023/A:1011325627223
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystalline supramolecular compound of composition {(C36H36N24O12)[Mo3O4(H2O)(6)Cl-3](2)}Cl-2. 14H(2)O was obtained by slow concentration of a hydrochloric solution of the cluster aqua complex [Mo3O4(H2O)(9)](4+) and macrocyclic cavitand cucurbituril (C36H36N24O12). The molecular and crystal structure of the supramolecular adduct was established by X-ray diffraction analysis.
引用
收藏
页码：494 / 496
页数：3
相关论文
共 10 条
[1]  
[Anonymous], 1998, SHELX 97 RELEASE 97
[2]   Unexpected guest-controlled formation of two-layered structure in supramolecular adduct of [W3S4(H2O)9]4+ and cucurbituril [J].
Dybtsev, DN ;
Gerasko, OA ;
Virovets, AV ;
Sokolov, MN ;
Fedin, VP .
INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (07) :345-349
[3]  
EMSLEY J, 1991, ELEMENTS, P292
[4]   Supramolecular assemblies based on cucurbituril adducts of hydrogen-bonded molybdenum and tungsten incomplete cuboidal aqua complexes [J].
Fedin, VP ;
Virovets, AV ;
Sokolov, MN ;
Dybtsev, DN ;
Gerasko, OA ;
Clegg, W .
INORGANIC CHEMISTRY, 2000, 39 (10) :2227-+
[5]   A supramolecular approach to the crystallization of chalcogenido bridged cluster aqua ions:: synthesis and structure of a cucurbituril adduct of the di-μ-disulfido Nb(IV)2 aqua ion [Nb2(μ-S2)2(H2O)8]4+ [J].
Fedin, VP ;
Virovets, AV ;
Dybtsev, DN ;
Gerasko, OA ;
Hegetschweiler, K ;
Elsegood, MRJ ;
Clegg, W .
INORGANICA CHIMICA ACTA, 2000, 304 (02) :301-304
[6]  
Lehn J. M., 1995, SUPRAMOLECULAR CHEM
[7]  
Mock W. L., 1996, COMPREHENSIVE SUPRAM, V2, P477
[8]   RATES OF ISOTOPIC OXYGEN-EXCHANGE WITH SOLVENT AND OXYGEN ATOM TRANSFER INVOLVING [MO3O4(OH2)9]4+ [J].
RODGERS, KR ;
MURMANN, RK ;
SCHLEMPER, EO ;
SHELTON, ME .
INORGANIC CHEMISTRY, 1985, 24 (09) :1313-1322
[9]  
Sokolov MN, 2000, ANGEW CHEM INT EDIT, V39, P1659, DOI 10.1002/(SICI)1521-3773(20000502)39:9<1659::AID-ANIE1659>3.0.CO
[10]  
2-8
1