Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems

被引：22

作者：

Sogaard, Alexander ^{[1
,2
]}

Scheuermeyer, Marlene ^{[1
]}

Boesmann, Andreas ^{[1
]}

Wasserscheid, Peter ^{[1
,3
]}

Riisager, Anders ^{[2
]}

机构：

[1] Friedrich Alexander Univ Erlangen Nurnberg, Lehrstuhl Chem Reakt Tech, Egerlandstr 3, D-91058 Erlangen, Germany

[2] Tech Univ Denmark, Ctr Catalysis & Sustainable Chem, Dept Chem, Kemitorvet, DK-2800 Lyngby, Denmark

[3] Forschungszentrum Julich, Helmholtz Inst Erlangen Nurnberg Erneuerbare Ener, Egerlandstr 3, D-91058 Erlangen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 14期

关键词：

REVERSIBLE DEHYDROGENATION; HETEROCYCLIC-COMPOUNDS; CARRIERS; STORAGE; RUTHENIUM;

D O I：

10.1039/c8cc09883b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ir-Complex catalysed hydrogen release/storage using a 2-methylindole/2-methylindoline Liquid Organic Hydrogen Carrier (LOHC) system is shown to be effective in a temperature range of 120 to 140 8C. In the form of a liquid-liquid biphasic reaction systemwithmolten [PPh4][NTf2] as catalyst immobilisation phase, the applied cationic Ir-complex can be easily separated and recycled enabling a small amount of ionic catalyst solution to store/release a large amount of hydrogen.

引用

页码：2046 / 2049

页数：4

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