Iodine-Catalyzed Three-Component Cascade Reaction for the Synthesis of Substituted 2-Phenylnaphtho[1,3]selenazoles under Transition-Metal-Free Conditions

被引：18

作者：

Chen, Wenqi ^{[1
]}

Zhu, Xiaoming ^{[2
]}

Wang, Fei ^{[1
]}

Yang, Yuan ^{[1
]}

Deng, Guobo ^{[1
]}

Liang, Yun ^{[1
]}

机构：

[1] Hunan Normal Univ, Natl & Local Joint Engn Lab New Petrochem Mat & F, Key Lab Assembly & Applicat Organ Funct Mol Hunan, Minist Educ,Key Lab Chem Biol & Tradit Chinese Me, Changsha 410081, Hunan, Peoples R China

[2] Hengyang Normal Univ, Coll Chem & Mat Sci, Hunan Prov Univ Key Lab Funct Organometall Mat, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Hunan, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 85卷 / 05期

基金：

中国国家自然科学基金;

关键词：

ONE-POT SYNTHESIS; C-S; SELENIUM POWDER; BENZOTHIAZOLES; ORGANOSELENIUM; DERIVATIVES; EFFICIENT; 2-AMINOBENZENETHIOLS; 2-ARYLBENZOTHIAZOLES; BENZOSELENAZOLES;

D O I：

10.1021/acs.joc.9b03154

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient molecular iodine-catalyzed three component cascade reaction for the construction of 2-phenylnaphtho[2,1-d] selenazoles from naphthalen-2-amine, aldehydes, and selenium powder has been developed. The present approach has the advantages of metal-free conditions, simple operation, and available raw materials. Moreover, the mechanism of the study proved that the reaction underwent a radical process.

引用

页码：3349 / 3357

页数：9

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