catena-poly[[[diaquamanganese(II)]-μ-oxalato]monohydrate]

被引：11

作者：

Fu, XC

Wang, CG ^{[1
]}

Li, MT

机构：

[1] Cent China Normal Univ, Dept Chem, Wuhan 430079, Hubei, Peoples R China

[2] W Anhui Univ, Dept Biol & Chem, Liu An 23700, Anhui, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805018805

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, {[Mn(C2O4)(H2O)(2)]center dot H2O}(n), the octahedrally coordinated Mn atom, lying on a twofold rotation axis, is bonded to four carboxyl O atoms from oxalate groups and two O atoms from two water molecules. By means of the bridging oxalate ligand, the title compound exhibits a one-dimensional chain structure. The crystal packing is stabilized by hydrogen bonds of the type O - H center dot center dot center dot O(oxalate).

引用

页码：M1348 / M1349

页数：2

共 7 条

[1]

*BRUK AXS INC, 1997, SHELXTL VERS 5 10

[2]

*BRUK AXS INC, 2000, SMART SAINT SADABS V

[3] 2 DIFFERENT (OXALATO)(BIPYRIDINE)COPPER(II) COMPLEXES IN ONE SINGLE-CRYSTAL - CRYSTAL-STRUCTURES AND MAGNETIC-PROPERTIES OF [CU2(BIPY)2(H2O)2(C2O4)]X2.[CU(BIPY)(C2O4)](X = NO3-, BF4- OR CLO4-) [J].