Indoor formaldehyde removal over CMK-3

被引:45
作者
An, Hyung Bum [1 ]
Yu, Mi Jin [1 ]
Kim, Ji Man [2 ,3 ]
Jin, Mingshi [2 ,3 ]
Jeon, Jong-Ki [4 ]
Park, Sung Hoon [5 ]
Kim, Seung-Soo [6 ]
Park, Young-Kwon [1 ,7 ]
机构
[1] Univ Seoul, Grad Sch Energy & Environm Syst Engn, Seoul 130743, South Korea
[2] Sungkyunkwan Univ, Sch Chem Mat Sci BK21, Dept Chem, Suwon 440746, South Korea
[3] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, South Korea
[4] Kongju Natl Univ, Dept Chem Engn, Cheonan 331717, South Korea
[5] Sunchon Natl Univ, Dept Environm Engn, Sunchon 540742, South Korea
[6] Kangwon Natl Univ, Dept Chem Engn, Samcheok 245711, South Korea
[7] Univ Seoul, Sch Environm Engn, Seoul 130743, South Korea
来源
NANOSCALE RESEARCH LETTERS | 2012年 / 7卷
关键词
low-concentration formaldehyde; mesoporous carbon; sulfuric acid; ammonia; activation; adsorption; CARBON; SILICA;
D O I
10.1186/1556-276X-7-7
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The removal of formaldehyde at low concentrations is important in indoor air pollution research. In this study, mesoporous carbon with a large specific surface area was used for the adsorption of low-concentration indoor formaldehyde. A mesoporous carbon material, CMK-3, was synthesized using the nano-replication method. SBA-15 was used as a mesoporous template. The surface of CMK-3 was activated using a 2N H2SO4 solution and NH3 gas to prepare CMK-3-H2SO4 and CMK-3-NH3, respectively. The activated samples were characterized by N-2 adsorption-desorption, X-ray diffraction, and X-ray photoelectron spectroscopy. The formaldehyde adsorption performance of the mesoporous carbons was in the order of CMK-3-NH3 > CMK-3-H2SO4 > CMK-3. The difference in the adsorption performance was explained by oxygen and nitrogen functional groups formed during the activation process and by the specific surface area and pore structure of mesoporous carbon.
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页数:6
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