Laser spectroscopy of the X 1Σ+ and B 1Π states of the LiRb molecule

被引:26
作者
Dutta, Sourav [1 ]
Altaf, Adeel [1 ]
Elliott, D. S. [1 ,2 ]
Chen, Yong P. [1 ,2 ]
机构
[1] Purdue Univ, Dept Phys, W Lafayette, IN 47907 USA
[2] Purdue Univ, Sch Elect & Comp Engn, W Lafayette, IN 47907 USA
基金
美国国家科学基金会;
关键词
ELECTRONIC-STRUCTURE;
D O I
10.1016/j.cplett.2011.05.059
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have studied the X (1)Sigma(+) and B (1)Pi states of (LiRb)-Li-7-Rb-85 using Laser Induced Fluorescence (LIF) Spectroscopy and Fluorescence Excitation Spectroscopy (FES). We extract molecular constants for levels v '' = 0-2 of the X (1)Sigma(+) state and levels v' = 0-20 of the B (1)Pi state. For the B (1)Pi state, we have observed rotational perturbations in the e-parity component of the v' = 2 level, and determined the dissociation energy. We discuss implications of our measurements in finding efficient photoassociation pathways for production of ultra-cold ground state LiRb molecules, and their detection via state selective ionization. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:7 / 11
页数:5
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