Recent developments in microwave-assisted, transition-metal-catalysed C-C and C-N bond-forming reactions

被引：164

作者：

Appukkuttan, Prasad ^{[1
]}

Van der Eycken, Erik ^{[2
]}

机构：

[1] Uppsala Univ, Dept Med Chem, S-75123 Uppsala, Sweden

[2] Univ Louvain, Dept Chem, B-3001 Louvain, Belgium

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 2008卷 / 07期

关键词：

microwave reactions; transition metals; cross-coupling; C-C coupling; palladium;

D O I：

10.1002/ejoc.200701056

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A selective over-view of the recent developments of microwave-assisted, transition-metal-catalysed C-C and C-N bond-forming reactions is presented. Microwave-assisted chemistry is a comparatively novel technique in the present-day synthetic world and has recently grown in an exponential manner, stretching from academia to a widely practiced technique in industry. Transition-metal-catalysed C-C and C-N bond-forming reactions represent one of the most interesting and well-investigated type of microwave-assisted reactions, evident from the plethora of available literature and patents in this area. Given the large number of articles published on the subject, we have made a very concise selection from the recent literature, covering manuscripts dealing with the subject from the period of the end 2004 until the first part of 2007.

引用

页码：1133 / 1155

页数：23

共 171 条

[1] Microwave chemistry: Out of the kitchen [J].

Adam, D .

NATURE, 2003, 421 (6923) :571-572

[2] Olefin metathesis: Catalyst development, microwave catalysis, and domino applications [J].

Aitken, SG ;

Abell, AD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2005, 58 (01) :3-13

[3] Synthesis of tricyclic heterocycles via a tandem aryl alkylation/heck coupling sequence [J].

Alberico, Dino ;

Rudolph, Alena ;

Lautens, Mark .

JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (03) :775-781

[4] Non-conventional methodologies for transition-metal catalysed carbon-carbon coupling: a critical overview. Part 1: The Heck reaction [J].

Alonso, F ;

Beletskaya, IP ;

Yus, M .

TETRAHEDRON, 2005, 61 (50) :11771-11835

[5] Dioxygen-promoted regioselective oxidative Heck arylations of electron-rich olefins with arylboronic acids [J].

Andappan, MMS ;

Nilsson, P ;

von Schenck, H ;

Larhed, M .

JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (16) :5212-5218

[6] Monodentate phosphines provide highly active catalysts for Pd-catalyzed C-N bond-forming reactions of heteroaromatic halides/amines and (H)N-heterocycles [J].

Anderson, Kevin W. ;

Tundel, Rachel E. ;

Ikawa, Takashi ;

Altman, Ryan A. ;

Buchwald, Stephen L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (39) :6523-6527

[7] Palladium-catalyzed amination of aryl nonaflates [J].

Anderson, KW ;

Mendez-Perez, M ;

Priego, J ;

Buchwald, SL .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (25) :9563-9573

[8] Microwave-enhanced synthesis of N-shifted buflavine analogues via a Suzuki-ring-closing metathesis protocol [J].

Appukkuttan, P ;

Dehaen, W ;

Van der Eycken, E .

ORGANIC LETTERS, 2005, 7 (13) :2723-2726

[9] Microwave-enhanced cadogan cyclization: An easy access to the 2-substituted carbazoles and other fused heterocyclic systems [J].

Appukkuttan, P ;

Van der Eycken, E ;

Dehaen, W .

SYNLETT, 2005, (01) :127-133

[10] A microwave-assisted click chemistry synthesis of 1,4-disubstituted 1,2,3-triazoles via a copper(I)-catalyzed three-component reaction [J].

Appukkuttan, P ;

Dehaen, W ;

Fokin, VV ;

Van der Eycken, E .

ORGANIC LETTERS, 2004, 6 (23) :4223-4225

← 1 2 3 4 5 6 7 8 9 10 →