Synthesis, structure, and physicochemical properties of lithium uranovanadate

被引：2

作者：

Suleimanov, EV ^{[1
]}

Chernorukov, NG ^{[1
]}

Karyakin, NV ^{[1
]}

Knyazev, AV ^{[1
]}

机构：

[1] Lobachevskii Nizhny Novgorod State Univ, Nizhnii Novgorod, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2003年 / 73卷 / 08期

关键词：

D O I：

10.1023/B:RUGC.0000007634.59886.d2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new chemical compound, lithium uranovanadate, was synthesized and studied by X-ray diffraction, IR spectroscopy, and thermography. Standard enthalpies of formation of lithium uranovanadate and its dihydrate at 298.15 K were determined by means of reaction and adiabatic vacuum calorimetry. Temperature dependence of heat capacity in the range 80-300 K was obtained for crystalline LiVUO(6)(.)2H(2)O and thermodynamic characteristics of its synthesis were calculated.

引用

页码：1163 / 1166

页数：4

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