Distinctive properties of Cp′M(NO)(alkyl)2 (M = MO, W) complexes

被引：22

作者：

Blackmore, IJ ^{[1
]}

Jin, X ^{[1
]}

Legzdins, P ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 17期

关键词：

D O I：

10.1021/om0504396

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This account summarizes our work with the title complexes, which are rare examples of electronically and coordinatively unsaturated transition-metal alkyls that can be isolated under ambient conditions. It first outlines the synthetic methods employed for the preparation of these compounds and then presents their distinctive physical properties. It then classifies the characteristic chemical properties of these complexes in terms of the reactivity being either metal or ligand based, and specific examples of particular transformations are illustrated with reference to the most studied systems.

引用

页码：4088 / 4098

页数：11

共 40 条

[1] α-agostic interactions in Cp*W(NO)(CH2CMe3)2 and related nitrosyl complexes [J].

Bau, R ;

Mason, SA ;

Patrick, BO ;

Adams, CS ;

Sharp, WB ;

Legzdins, P .

ORGANOMETALLICS, 2001, 20 (22) :4492-4501

[2] NOVEL ROUTE TO THE UNSYMMETRICAL DIALKYL COMPLEX CPW(NO)(CH2SIME3)(CH2CPH3) AND FORMATION OF METALLACYCLES BY THERMOLYSIS OF CPW(NO)(CH2SIME3)(CH2CR2PH) (R=ME, PH) [J].

BRUNET, N ;

DEBAD, JD ;

LEGZDINS, P ;

TROTTER, J ;

VELTHEER, JE ;

YEE, VC .

ORGANOMETALLICS, 1993, 12 (11) :4572-4579

[3] ELECTRONIC CONNECTIONS BETWEEN EXCEPTIONAL LOW-VALENT AND HIGH-VALENT ORGANOMETALLIC COMPOUNDS - THE CASE OF CPM(L)R2 (M = W, RE L = NO, O R = ALKYL) [J].

BURSTEN, BE ;

CAYTON, RH .

ORGANOMETALLICS, 1987, 6 (09) :2004-2005

[4] DICARBONYL(ETA-5-CYCLOPENTADIENYL)NITROSYL COMPLEXES OF CHROMIUM, MOLYBDENUM, AND TUNGSTEN [J].

CHIN, TT ;

HOYANO, JK ;

LEGZDINS, P ;

MALITO, JT .

INORGANIC SYNTHESES, 1990, 28 :196-198

[5] REACTIVITY OF THE LEWIS-ACIDS CP-ASTERISK-M(NO)(CH2CME3)CL [M = MO, W] AND RELATED COMPLEXES [J].

DEBAD, JD ;

LEGZDINS, P ;

RETTIG, SJ ;

VELTHEER, JE .

ORGANOMETALLICS, 1993, 12 (07) :2714-2725

[6] GENERATION AND REACTIVITY OF CP-ASTERISK-W(NO)(CH(2)SIME(3))H, A 16-VALENCE-ELECTRON ALKYL HYDRIDE COMPLEX [J].

DEBAD, JD ;

LEGZDINS, P ;

LUMB, SA ;

BATCHELOR, RJ ;

EINSTEIN, FWB .

ORGANOMETALLICS, 1995, 14 (05) :2543-2555

[7] SYNTHESIS AND CHARACTERIZATION OF THE ASYMMETRIC COMPLEXES CP-ASTERISK-W(NO)(R)(R') [R, R' = ALKYL, ARYL] AND REGIOSELECTIVE INSERTIONS OF CO INTO THEIR W-C SIGMA-BONDS [J].

DEBAD, JD ;

LEGZDINS, P ;

BATCHELOR, RJ ;

EINSTEIN, FWB .

ORGANOMETALLICS, 1993, 12 (06) :2094-2102

[8] NITROSYL N-O BOND-CLEAVAGE INDUCED BY REDUCING AGENTS - SYNTHESIS AND CHARACTERIZATION OF NOVEL NITRIDO-BRIDGED BIMETALLIC COMPLEXES OF MOLYBDENUM AND TUNGSTEN [J].

DEBAD, JD ;

LEGZDINS, P ;

REINA, R ;

YOUNG, MA ;

BATCHELOR, RJ ;

EINSTEIN, FWB .

ORGANOMETALLICS, 1994, 13 (11) :4315-4321

[9] REACTIONS OF 16-ELECTRON CP'M(NO)R2 COMPOUNDS [M = MO, W R = ALKYL, ARYL] WITH CARBON-MONOXIDE [J].

DRYDEN, NH ;

LEGZDINS, P ;

LUNDMARK, PJ ;

RIESEN, A ;

EINSTEIN, FWB .

ORGANOMETALLICS, 1993, 12 (06) :2085-2093

[10] ORGANOMETALLIC NITROSYL CHEMISTRY .45. IMPROVED SYNTHESES OF CYCLOPENTADIENYL DICHLORO NITROSYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN - UTILITY OF PHOSPHORUS-PENTACHLORIDE AS A CHLORINATING AGENT [J].

DRYDEN, NH ;

LEGZDINS, P ;

BATCHELOR, RJ ;

EINSTEIN, FWB .

ORGANOMETALLICS, 1991, 10 (06) :2077-2081

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