Salt effect on the isobaric vapor-liquid equilibrium of the methyl acetate plus methanol system

被引：24
|
作者：
Iliuta, MC
Thyrion, FC
Landauer, OM
机构：
[1] UNIV CATHOLIQUE LOUVAIN,INST CHEM ENGN,B-1348 LOUVAIN,BELGIUM
[2] UNIV POLITEHN BUCHAREST,FAC IND CHEM,DEPT APPL PHYS CHEM,R-78126 BUCHAREST,ROMANIA
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1996年 / 41卷 / 04期
关键词：
D O I：
10.1021/je960020+
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The effect of sodium thiocyanate at constant salt mole fraction from 0.01 to 0.05 and at saturation on the vapor-liquid equilibrium (VLE) of methyl acetate + methanol has been studied at 101.32 kPa using a modified Othmer equilibrium still. The salt exhibited both salting-in and salting-out effects on the methyl acetate, the azeotrope being eliminated at saturation. The results were correlated using the extended UNIQUAC model of Sander et al. and the electrolytic NRTL model of Mock et al.
引用
收藏
页码：713 / 717
页数：5
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