Preparation of polyurethane wood adhesives by polyols formulated with polyester polyols based on castor oil

被引：70

作者：

Moghadam, Peyman Najafi ^{[1
]}

Yarmohamadi, Mazaher ^{[2
]}

Hasanzadeh, Reza ^{[1
]}

Nuri, Sirus ^{[2
]}

机构：

[1] Urmia Univ, Fac Chem, Dept Organ Chem, Orumiyeh, Iran

[2] Urmia Univ, Fac Chem, Dept Appl Chem, Orumiyeh, Iran

来源：

INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES | 2016年 / 68卷

关键词：

Castor oil; Dicarboxylic acid; Polyester polyol; Polyurethane wood adhesive; MECHANICAL-PROPERTIES; RENEWABLE RESOURCE; ELASTOMERS;

D O I：

10.1016/j.ijadhadh.2016.04.004

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The aim of this work was the synthesis of polyester polyols from renewable sources as one of the important compounds of polymeric polyurethane (PU) adhesives. The polyester polyols were synthesized by condensation polymerization of different dicarboxylic acids with castor oil and the reaction conditions were in agreement with green chemistry principles. The preparation of PU wood adhesives was carried out by the reaction of each obtained polyester polyol with 4, 4'-diphenylmethane diisocyanate (MDI). The adhesive performance was improved by mixing the obtained polyester polyols with polypropylene glycol (PPG 400) and butanediol (BD). Different NCO/OH ratios were used to obtain adhesives with appropriate properties. The structures of the synthesized polyesters and adhesives were characterized by FTIR, thermogravimetric analysis (TGA) and lap shear strength values were also determined in various conditions such as cold water, hot water, acid and alkali solutions. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：273 / 282

页数：10

共 37 条

[1] Recent developments in polyurethanes and poly(acrylates) interpenetrating polymer networks [J].

Athawale, WD ;

Kolekar, SL ;

Raut, SS .

JOURNAL OF MACROMOLECULAR SCIENCE-POLYMER REVIEWS, 2003, C43 (01) :1-26

[2] Mechanical properties of simultaneous interpenetrating polymer networks of Castor oil based polyurethane and polystyrene [J].

Bai, S ;

Khakhar, DV ;

Nadkarni, VM .

POLYMER, 1997, 38 (17) :4319-4323

[3] Thermal and mechanical properties of simultaneous and sequential full-interpenetrating polymer networks [J].

Bartolotta, A ;

Di Marco, G ;

Lanza, M ;

Carini, G ;

D'Angelo, G ;

Tripodo, G ;

Fainleib, A ;

Danilenko, I ;

Grytsenko, V ;

Sergeeva, L .

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 370 (1-2) :288-292

[4]

Burhan A, 2014, INT J ADHES ADHES, V49, P90

[5] Biodegradation of Polyurethane Derived from Castor Oil [J].

Cangemi, Jose M. ;

dos Santos, Antonia M. ;

Neto, Salvador C. ;

Chierice, Gilberto O. .

POLIMEROS-CIENCIA E TECNOLOGIA, 2008, 18 (03) :201-206

[6]

da Cunha F.O. Vieira., 2004, Material Research, V7, P539, DOI DOI 10.1590/S1516-14392004000400006

[7] Polyurethane adhesive system from biomaterial-based polyol for bonding wood [J].

Desai, SD ;

Patel, JV ;

Sinha, VK .

INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2003, 23 (05) :393-399

[8] Urea-formaldehyde (UF) adhesive resins for wood [J].

Dunky, M .

INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 1998, 18 (02) :95-107

[9]

Fedorovskaya EA, 1997, COLOR RES APPL, V22, P96, DOI 10.1002/(SICI)1520-6378(199704)22:2<96::AID-COL5>3.0.CO

[10]

2-Z

← 1 2 3 4 →