Investigation on NiWO4/PANI composite as an electrode material for energy storage devices

被引:41
|
作者
Rajkumar, S. [1 ]
Gowri, S. [2 ]
Dhineshkumar, S. [1 ]
Merlin, J. Princy [1 ]
Sathiyan, A. [1 ]
机构
[1] Bharathidasan Univ, Bishop Heber Coll Autonomous, PG & Res Dept Chem, Tiruchirappalli 620017, Tamil Nadu, India
[2] Bharathidasan Univ, Cauvery Coll Women, Dept Phys, Tiruchirappalli 620018, Tamil Nadu, India
关键词
ENHANCED ELECTROCHEMICAL PERFORMANCE; GRAPHENE OXIDE NANOCOMPOSITE; HIGH-RATE-CAPABILITY; FACILE SYNTHESIS; CARBON CLOTH; NI FOAM; ASYMMETRIC SUPERCAPACITORS; CATHODE MATERIAL; NANOWIRE ARRAYS; NANOPARTICLES;
D O I
10.1039/d1nj03831a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
With the fast exhaustion of fossil fuels, the need for new energy storage materials to meet the world's massive energy demand has increased tremendously. Inorganic components with conducting polymer based materials for supercapacitors (SCs) have seen significant research breakthroughs in recent years. Herein, we report an efficient material of a NiWO4/PANI composite, synthesised successfully via a polymerization route. The composite was characterized by different physico-chemical techniques. NiWO4/PANI exhibited a unique morphology with more redox sites, which enhanced the electrochemical performance. Moreover, the NiWO4/PANI electrode delivered a high specific capacity (C-s) of 854 C g(-1) at a current density of 1 A g(-1) and a considerable capacitance retention of 91.6% even after 5000 GCD cycles at 2 A g(-1). The advantage of the high conductivity of PANI and short ion transport channels of NiWO4, combined with the synergistic factor of NiWO4 and PANI, resulted in an improved specific capacity. Also, this work puts forward an alternate energy storage material to fabricate high performance SCs.
引用
收藏
页码:20612 / 20623
页数:12
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