Synthesis of Dichlorobis(1,4-dimesityl-1H-1,2,3-triazol-5-ylidene)palladium [PdCl2(TMes)2] and Its Application to Suzuki-Miyaura Coupling Reaction

被引：64

作者：

Nakamura, Tatsuhito ^{[1
]}

Ogata, Kenichi ^{[1
]}

Fukuzawa, Shin-ichi ^{[1
]}

机构：

[1] Chuo Univ, Dept Appl Chem, Inst Sci & Engn, Bunkyo Ku, Tokyo 1128551, Japan

来源：

CHEMISTRY LETTERS | 2010年 / 39卷 / 09期

基金：

日本学术振兴会;

关键词：

N-HETEROCYCLIC CARBENE; PALLADIUM COMPLEXES; LIGANDS; IMIDAZOLIUM; IRIDIUM; CATALYSTS; CHEMISTRY;

D O I：

10.1246/cl.2010.920

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium complex bearing a novel NHC-ligand derived from 1,4-dimesityl-1,2,3-tirazole was prepared. The complex catalyzed the Suzuki-Miyaura coupling reaction with aryl chloride successfully to give biaryls in excellent yields, particularly very effective for the sterically hindered reaction between o-substituted arylchlorides and o-substituted phenylboronic acids.

引用

页码：920 / 922

页数：3

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