Effects of Hardware Design and Operation Conditions on PEM Fuel Cell Water Flooding

被引:34
作者
Zhang, Jianlu [1 ]
Li, Hui [1 ]
Shi, Zheng [1 ]
Zhang, Jiujun [1 ]
机构
[1] Natl Res Council Canada, Inst Fuel Cell Innovat, Vancouver, BC V6T 1W5, Canada
关键词
AC impedance spectroscopy (EIS); Flow field; Mass transfer; Operating conditions; Proton-exchange membrane (PEM) fuel cells; Teflon (PTFE) loading; Water flooding; FLOW-FIELD; DIAGNOSTIC-TOOL; 2-PHASE FLOW; PERFORMANCE; TRANSPORT; PRESSURE; PARALLEL;
D O I
10.1080/15435075.2010.515185
中图分类号
O414.1 [热力学];
学科分类号
摘要
In this paper, membrane electrode assemblies were constructed using catalyst-coated membranes to investigate proton-exchange membrane fuel cell water flooding. Two major fuel cell hardware variations, namely flowfield design and Teflon loading of the gas diffusion layer (GDL), were tested to explore their effects on water flooding. A flowfield with triple serpentine flow channels showed heavier water flooding than that with single serpentine flow channels. Increasing the Teflon loading in the GDL reduced water flooding effectively. Several fuel cell operating conditions, including air stoichiometry, current density, relative humidity (RH), backpressure, and temperature, were also tested to identify their effects on water flooding. It was observed that the water flooding severity increased with decreasing air stoichiometry, as well as with increasing temperature, RH, backpressure, and current density. Among these operation conditions, air stoichiometry (or air flow rate) and RH played more important roles in reducing water flooding.
引用
收藏
页码:461 / 474
页数:14
相关论文
共 27 条
[1]   Relationship between pressure drop and cell resistance as a diagnostic tool for PEM fuel cells [J].
Barbir, F ;
Gorgun, H ;
Wang, X .
JOURNAL OF POWER SOURCES, 2005, 141 (01) :96-101
[2]  
BENZIGER JB, 2007, ECS T, V12, P67
[3]   Solid acids as fuel cell electrolytes [J].
Haile, SM ;
Boysen, DA ;
Chisholm, CRI ;
Merle, RB .
NATURE, 2001, 410 (6831) :910-913
[4]   A PEM fuel cell for combined measurement of current and temperature distribution, and flow field flooding [J].
Hakenjos, A ;
Muenter, H ;
Wittstadt, U ;
Hebling, C .
JOURNAL OF POWER SOURCES, 2004, 131 (1-2) :213-216
[5]   Diagnostic tool to detect electrode flooding in proton-exchange-membrane fuel cells [J].
He, WS ;
Lin, GY ;
Nguyen, TV .
AICHE JOURNAL, 2003, 49 (12) :3221-3228
[6]   Flooding of gas diffusion backing in PEFCs - Physical and electrochemical characterization [J].
Ihonen, J ;
Mikkola, M ;
Lindbergh, G .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (08) :A1152-A1161
[7]  
Larminie J., 2001, FUEL CELL SYSTEMS EX
[8]   Fundamental understanding of liquid water effects on the performance of a PEMFC with serpentine-parallel channels [J].
Le, Anh Dinh ;
Zhou, Biao .
ELECTROCHIMICA ACTA, 2009, 54 (08) :2137-2154
[9]   Detection of membrane drying, fuel cell flooding, and anode catalyst poisoning on PEMFC stacks by electrochemical impedance spectroscopy [J].
Le Canut, JM ;
Abouatallah, RM ;
Harrington, DA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (05) :A857-A864
[10]   A review of water flooding issues in the proton exchange membrane fuel cell [J].
Li, Hui ;
Tang, Yanghua ;
Wang, Zhenwei ;
Shi, Zheng ;
Wu, Shaohong ;
Song, Datong ;
Zhang, Jianlu ;
Fatih, Khalid ;
Zhang, Jiujun ;
Wang, Haijiang ;
Liu, Zhongsheng ;
Abouatallah, Rami ;
Mazza, Antonio .
JOURNAL OF POWER SOURCES, 2008, 178 (01) :103-117