Mesoporous nickel hydroxyapatite nanocomposite for microwave-assisted Henry reaction

被引:40
作者
Neelakandeswari, N. [1 ]
Sangami, G. [1 ]
Emayavaramban, P. [1 ]
Karvembu, R. [2 ]
Dharmaraj, N. [1 ]
Kim, Hak Yong [3 ]
机构
[1] Bharathiar Univ, Dept Chem, Coimbatore 641046, Tamil Nadu, India
[2] Natl Inst Technol, Dept Chem, Tiruchirappalli 620015, Tamil Nadu, India
[3] Chonbuk Natl Univ, Dept Text Engn, Inorgan Organ Nanomat Res Lab, Chonju 561756, South Korea
关键词
Nickel hydroxyapatite; Green chemistry; Henry reaction; Heterogeneous catalysis; HETEROGENEOUS CATALYST; ORGANIC-CHEMISTRY; ALDEHYDES; MICHAEL;
D O I
10.1016/j.tetlet.2012.03.086
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The utility of nickel hydroxyapatite nanocomposite (Ni-HAp) as a green catalyst for solvent free, microwave-assisted Henry reaction using nitromethane and a series of aromatic aldehydes as substrates is presented. The selected catalyst performed well to afford the respective nitrostyrenes which were quantified by gas chromatography equipped with a mass spectral detector (GC-MS). A few of the products were identified from the respective nuclear magnetic resonance (NMR) spectral data. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2980 / 2984
页数:5
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