Synthesis and spectroscopic characterization of meso-tetraarylporphyrins with fused phenanthrene rings

被引：0
作者：
Xu, HJ
Shen, Z [1 ]
Okujima, T
Ono, N
You, XZ
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Ehime Univ, Fac Sci, Dept Chem, Matsuyama, Ehime 7908577, Japan
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 06期
关键词：
exocyclic rings; phenanthrene ring; ring-fused porphyrins; synthesis;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of meso-tetraaryl porphyrins with fused phenanthrene rings have been synthesized from boron trifluoride-catalyzed Lindsey condensation of phenanthro[9, 10-c]pyrrole with various para-substituted arylaldehydes at low temperature. Their structures were characterized by UV-vis, H-1 NMR, and mass spectroscopies. The UV-vis spectra of these compounds showed remarkable bathochromic shift of the Soret band to the wavelength around 577 nm and Q-bands into the near-infrared region. (c) 2005 Elsevier Ltd. All rights reserved.
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页码：931 / 934
页数：4
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