Cross dipole stacking in the crystal of distyrylbenzene derivative: The approach toward high solid-state luminescence efficiency

被引:348
作者
Xie, ZQ
Yang, B
Li, F
Cheng, G
Liu, LL
Yang, GD
Xu, H
Ye, L
Hanif, M
Liu, SY
Ma, DG
Ma, YG [1 ]
机构
[1] Jilin Univ, Key Lab Supramol Struct & Mat, Minist Educ, Changchun 130012, Peoples R China
[2] Jilin Univ, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
关键词
D O I
10.1021/ja054661d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Through adding two substituent phenyl groups on distyrylbenzene, we have obtained the cross stacking of 2,5-diphenyl-1,4-distyrylbenzene with two trans double bonds (trans-DPDSB) in crystalline state. In such a cross-stacking mode, the solid-state emission exhibits high-intensity, having characteristics similar to its single molecule. The organic light-emiiting diodes (OLEDs) with attractive performance have been achieved using trans-DPDSB as a light-emitting layer, and the amplified spontaneous emission of the needlelike crystals has been observed. Copyright © 2005 American Chemical Society.
引用
收藏
页码:14152 / 14153
页数:2
相关论文
共 30 条
  • [1] BOURROUGHES JH, 1990, NATURE, V347, P539
  • [2] Cornil J, 2001, ADV MATER, V13, P1053, DOI 10.1002/1521-4095(200107)13:14<1053::AID-ADMA1053>3.0.CO
  • [3] 2-7
  • [4] Influence of interchain interactions on the absorption and luminescence of conjugated oligomers and polymers:: A quantum-chemical characterization
    Cornil, J
    dos Santos, DA
    Crispin, X
    Silbey, R
    Brédas, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (06) : 1289 - 1299
  • [5] 1,3,6,8-tetraphenylpyrene derivatives:: Towards fluorescent liquid-crystalline columns?
    de Halleux, V
    Calbert, JP
    Brocorens, P
    Cornil, J
    Declercq, JP
    Brédas, JL
    Geerts, Y
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (07) : 649 - 659
  • [6] FORSTER T, 1959, DISCUSS FARADAY SOC, P7
  • [7] New developments in the photonic applications of conjugated polymers
    Hide, F
    DiazGarcia, MA
    Schwartz, BJ
    Heeger, AJ
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (10) : 430 - 436
  • [8] Fluorescent hexacatenar liquid crystals
    Hoag, B
    Gin, DL
    Theissl, U
    Zojer, E
    Leising, G
    [J]. LUMINESCENT MATERIALS, 1999, 560 : 277 - 282
  • [9] Green light-emitting diodes from poly(2-dimethyloctylsilyl-1,4,-phenylenevinylene)
    Hwang, DH
    Kim, ST
    Shim, HK
    Holmes, AB
    Moratti, SC
    Friend, RH
    [J]. CHEMICAL COMMUNICATIONS, 1996, (19) : 2241 - 2242
  • [10] EXCIMERS AND EXCIPLEXES OF CONJUGATED POLYMERS
    JENEKHE, SA
    OSAHENI, JA
    [J]. SCIENCE, 1994, 265 (5173) : 765 - 768