Ammonium Octahydrotriborate (NH4B3H8): New Synthesis, Structure, and Hydrolytic Hydrogen Release

被引：60

作者：

Huang, Zhenguo ^{[2
]}

Chen, Xuenian ^{[1
,2
]}

Yisgedu, Teshome ^{[2
]}

Meyers, Edward A. ^{[1
]}

Shore, Sheldon G. ^{[1
]}

Zhao, Ji-Cheng ^{[2
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

[2] Ohio State Univ, Dept Mat Sci & Engn, Columbus, OH 43210 USA

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 08期

关键词：

BOROHYDRIDE; BORANE; TRIBORANE; STORAGE;

D O I：

10.1021/ic2000987

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A metathesis reaction between unsolvated NaB3H8 and NH4Cl provides a simple and high-yield synthesis of NH4B3H8. Structure determination through X-ray single crystal diffraction analysis reveals weak N-H delta+---H delta--B interaction in NH4B3H8 and strong N-H delta+-H delta--B interaction in NH4B3H8 center dot 18-crown-6 center dot THF adduct. Pyrolysis of NH4B3H8 leads to the formation of hydrogen gas with appreciable amounts of other volatile boranes below 160 degrees C. Hydrolysis experiments show that upon addition of catalysts, NH4B3H8 releases up to 7.5 materials wt % hydrogen.

引用

页码：3738 / 3742

页数：5

共 41 条

[1] Supramolecular cation assemblies of hydrogen-bonded (NH4+/NH2NH3+)(crown ether) in [Ni(dmit)2]-based molecular conductors and magnets
Akutagawa, T
Hasegawa, T
Nakamura, T
Inabe, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (30) : 8903 - 8911
[2] Transport characteristics of dehydrogenated ammonia borane and sodium borohydride spent fuels
Basu, Sumit
Diwan, Moiz
Abiad, Mohamad G.
Zheng, Yuan
Campanella, Osvaldo H.
Varma, Arvind
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (05) : 2063 - 2072
[3] A study of catalytic hydrolysis of concentrated ammonia borane solutions
Brockman, Alan
Zheng, Yuan
Gore, Jay
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (14) : 7350 - 7356
[4] Ruthenatetraboranes: Molecular structure of [Ru(B3H8)(PPh(3)){kappa(3)-HB(pz)3}] (pz=pyrazol-1-yl)
Burns, ID
Hill, AF
Williams, DJ
[J]. INORGANIC CHEMISTRY, 1996, 35 (09) : 2685 - 2687
[5] Carvalho D. A. L., 1971, U. S. Patent, Patent No. [3,564,561, 3564561]
[6] Deng Y., 1986, Chinese Pat., Patent No. [CN85100253A, 85100253]
[7] Synthesis and characterization of the homoleptic octahydrotriborate complex Cr(B3H8)2 and its Lewis base adducts
Goedde, Dean M.
Windler, G. Kenneth
Girolami, Gregory S.
[J]. INORGANIC CHEMISTRY, 2007, 46 (07) : 2814 - 2823
[8] NOVEL SYNTHESIS OF TRIBOROHYDRIDE ANION, -B3H8
GRAYBILL, BM
RUFF, JK
HAWTHORNE, MF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (12) : 2669 - &
[9] Synthesis of ammonia borane for hydrogen storage applications
Heldebrant, David J.
Karkamkar, Abhi
Linehan, John C.
Autrey, Tom
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2008, 1 (01) : 156 - 160
[10] Hough W. V., 1967, US Pat., Patent No. [3,313,603, 3313603]

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