RENEWABLE NATURAL RAW MATERIALS. STRUCTURE, PROPERTIES, APPLICATION PROSPECTS

被引：28

作者：

Teptereva, G. A. ^{[1
]}

Pakhomov, S., I ^{[2
]}

Chetvertneva, I. A. ^{[1
]}

Karimov, E. H. ^{[3
]}

Egorov, M. P. ^{[4
]}

Movsumzade, E. M. ^{[1
]}

Evstigneev, E., I ^{[5
]}

Vasiliev, A. V. ^{[5
]}

Sevastyanova, M., V ^{[1
]}

Voloshin, A., I ^{[6
]}

Nifantyev, N. E. ^{[4
]}

Nosov, V. V. ^{[6
]}

Dokichev, V. A. ^{[7
]}

Babaev, E. R. ^{[8
]}

Rogovina, S. Z. ^{[9
]}

Berlin, A. A. ^{[9
]}

Fakhreeva, A., V ^{[7
]}

Baulin, O. A. ^{[1
]}

Kolchina, G. Yu ^{[10
]}

Voronov, M. S. ^{[11
]}

Staroverov, D., V ^{[11
]}

Kozlovsky, I. A. ^{[11
]}

Kozlovsky, R. A. ^{[11
]}

Tarasova, N. P. ^{[11
]}

Zanin, A. A. ^{[11
]}

Krivoborodov, E. G. ^{[11
]}

Karimov, O. Kh ^{[12
]}

Flid, V. R. ^{[12
]}

Loginova, M. E. ^{[1
]}

机构：

[1] Ufa State Petr Tech Univ, Kosmonavtov St 1, Ufa 450062, Russia

[2] Minist Educ & Sci Russian Federat, Dept Attestn Sci & Sci Pedag Workers, Bryusov Line 21, Moscow 125009, Russia

[3] Ltd Liabil Co, Prod & Commercial Co Poliplast, Levyi Bereg St 36, Ishimbay 453206, Bashkortostan, Russia

[4] RAS, ND Zelinsky Inst Organ Chem, Leninsky Ave 47, Moscow 119991, Russia

[5] St Petersburg State Forest Engn Univ, Inst Sky Line 5, St Petersburg 194021, Russia

[6] RN BashNIPIneft LLC, Sochinskaya St 12, Ufa 450103, Russia

[7] RAS, Ufa Inst Chem UFRCe, Oktyabrya Ave 69, Ufa 450054, Russia

[8] Natl Acad Sci Azerbaijan, Inst Addit Chem, Boyukshorskoe Highway,2062 Th Block, AZ-1029 Baku, Azerbaijan

[9] RAS, NN Semenov Inst Chem Phys, Kosygina St 4, Moscow 119991, Russia

[10] Bashkir State Univ, Sterlitamak Branch, Lenina St 49, Sterlitamak 453120, Russia

[11] DI Mendeleev Russian Univ Chem Technol, Miusskaya Sq 9, Moscow 125047, Russia

[12] MIREA Russian Technol Univ, Vernadsky Ave 86, Moscow 119571, Russia

来源：

IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA | 2021年 / 64卷 / 09期

关键词：

green chemistry; vegetable raw materials; lignin; lignosulfonates; cellulose; polysaccharides; hemicelluloses; carboxymethylcellulose; compositions; biodegradability; RADIATION-INDUCED POLYMERIZATION; KINETIC HYDRATE INHIBITORS; IONIC LIQUID; POLY(LACTIC ACID); CARBON-FIBERS; KRAFT LIGNIN; ADSORPTION CHARACTERISTICS; CARBOXYMETHYL CELLULOSE; RADICAL POLYMERIZATION; MECHANICAL-PROPERTIES;

D O I：

10.6060/ivkkt.20216409.6465

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The review considers the current ideas of a relatively new field of "green chemistry" in the field of chemical processing of renewable natural plant raw materials. For a number of processes, the ways, methods and some technological aspects of obtaining new compounds and reagent systems, biodegradable compositions and "green chemistry" products that are in demand in various sectors of the economy, industry and life support of society are shown. The article presents the results of the analysis of Russian and world reserves of forest resources according to authoritative modern sources and proposals for their conservation and restoration. The problems of biorefiling of plant raw materials are described, one of which is the valorization of lignin-the aromatic component of the chemical composition of wood. It is proposed to obtain biodegradable systems and compositions based on the by-product of wood processing lignosulfonate of a neutral production method characterized by a high content of polysaccharides in the hemicellulose of the carbohydrate part of wood after the separation of cellulose. The ways of using modified cellulose products as inhibitors of salt deposition and gas hydrate formation, and the areas of their application in oilfield chemistry are shown. Lignin and other components of plant resources have long been the basis of various classes of fibers of natural origin, including plant and animal origin, artificial fibers. In the sector of creating materials with new properties that have a wide range of practical applications, the review describes the production of PLA polylactide synthesized from lactic acid as a modern alternative to many synthetic polymers obtained from refined petroleum products. For the products of the interaction of ammonium lactate and n-butyl alcohol, a kinetic model for the production of butyl lactate, an intermediate product of green chemistry, is described. The results of the study of a specific class of compounds - ionic liquids - traditionally considered as so-called "green solvents" are presented. An approach to the creation of a mathematical model by calculating the adsorption characteristics for evaluating the effectiveness of systems and composites based on biodegradable polymers in the direction of "green chemistry" is proposed.

引用

页码：5 / 122

页数：118

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