Viscoelastic properties of concentrated dispersions in water of soy lecithin

被引:56
作者
Manconi, M
Aparicio, J
Vila, AO
Pendás, J
Figueruelo, J
Molina, F [1 ]
机构
[1] Univ Valencia, Unidad Invest Coliodes, Dpt Quim Fis, Valencia, Spain
[2] Univ Cagliari, Dpt Farm Chim Tecnol, Cagliari, Italy
[3] Ctr Nacl Invest Cient, Lab Criobiol & Liofilizac, Havana, Cuba
关键词
soy lecithin; phospholipids; vesicles; viscoclastic properties; rheopexy;
D O I
10.1016/S0927-7757(03)00249-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Viscoelastic properties of soy lecithin dispersions at 60, 120, 180 and 240 g 1(-1) in water have been studied as a function of ionic strength (NaCl concentrations in the range 10(-5)-10(-2) mol 1(-1)) and of preparation method (sonication, freezing-unfreezing). Viscosity measurements of sonicated dispersions in a rotatory viscometer show Newtonian and plastic (Bingham) behavior, whereas the frozen-unfrozen dispersions show a spectacular change in their viscoelastic properties, that is, a non-Newtonian behavior with pseudoplastic characteristics and rheopexy. These properties have been related to electrokinetic characteristics of the segregated vesicles in each case. A decrease in !;potential (in absolute value) of vesicles results on an increase in the hysteresis loop area of the parents dispersions. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:141 / 145
页数:5
相关论文
共 12 条
[1]   EFFECT OF THE OSMOTIC CONDITIONS ON THE VALUE OF ZETA-POTENTIAL OF DMPC MULTILAMELLAR LIPOSOMES [J].
ALONSO, JM ;
LLACER, C ;
VILA, AO ;
FIGUERUELO, JE ;
MOLINA, FJ .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1995, 95 (01) :11-14
[2]   HYDRODYNAMIC STRESS ON FRACTAL AGGREGATES OF SPHERES [J].
BOSSIS, G ;
MEUNIER, A ;
BRADY, JF .
JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (07) :5064-5070
[3]   Analysis of the interaction with biomembrane models of the HAV-VP3(101-121) sequence conjugated to synthetic branched chain polypeptide carriers with a poly[L-lysine] backbone [J].
Garcia, M ;
Nagy, IB ;
Alsina, MA ;
Mezo, G ;
Reig, F ;
Hudecz, F ;
Haro, I .
LANGMUIR, 1998, 14 (07) :1861-1869
[4]   Engineering liposomes for drug delivery: Progress and problems [J].
Gregoriadis, G .
TRENDS IN BIOTECHNOLOGY, 1995, 13 (12) :527-537
[5]   THE SWELLING OF EGG LECITHIN IN WATER [J].
HARBICH, W ;
HELFRICH, W .
CHEMISTRY AND PHYSICS OF LIPIDS, 1984, 36 (01) :39-63
[6]  
Lasic D., 1998, Medical Applications of Liposomes
[7]  
Lasic D.D., 1996, HDB NONMEDICAL APPL
[8]   Intrinsic viscosity and the electrical polarizability of arbitrarily shaped objects [J].
Mansfield, ML ;
Douglas, JF ;
Garboczi, EJ .
PHYSICAL REVIEW E, 2001, 64 (06) :16-061401
[9]   Interaction of ionic compounds with multilamellar liposomes. An electrokinetic model [J].
Molina, F ;
Llacer, C ;
Vila, AO ;
Puchol, A ;
Figueruelo, J .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1998, 140 (1-3) :91-101
[10]   Geometrical and thermodynamical considerations about the lipid vesicles formation in water (II. Multilamellar vesicles) [J].
Rodríguez-Flores, C ;
Vila, AO ;
Figueruelo, J ;
Molina, F .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2001, 191 (03) :233-240