Hydrothermal synthesis, crystal structure and third-order non-linear optical property of a novel three-dimensional supramolecular network compound [Ni(IN)2(H2O)4] (IN = isonicotinate)

被引：16
作者：
Ma, TH
Yu, JH
Ye, L
Xu, JQ [1 ]
Wang, TG
Lü, CH
机构：
[1] Jilin Univ, Coll Chem, Changchun 130023, Jilin, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Jilin, Peoples R China
[3] Mudanjiang Normal Coll, Dept Chem, Mudanjiang 157012, Heilongjiang, Peoples R China
[4] Jilin Univ, Key Lab Supramol Struct & Mat, Ministry Educ, Changchun 130023, Jilin, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2003年 / 654卷 / 1-3期
基金：
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词：
crystal engineering; supramolecular structure; isonicotinate acid; hydrothermal synthesis;
D O I：
10.1016/S0022-2860(03)00179-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A three-dimensional supramolecular compound [Ni(IN)(2)(H2O)(4)] 1 has been rationally designed and synthesized by hydrothermal method, and the structure was characterized with elemental analysis, FT-IR spectrum and X-ray diffractometer. In the packing structure, the stronger intermolecular O-(HO)-O-... hydrogen-bonded and pi-pi stacking interactions are the most significant factors of controlling the novel supramolecular sheet fashion for the title compound. The third-order non-linear optical property of compound 1 was also investigated, and it exhibits nicer reverse saturable absorption and self-focusing performance. (C) 2003 Elsevier Science B.V. All rights reserved.
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收藏
页码：47 / 53
页数：7
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