Electrochemical atomic force microscopy of two-dimensional trinuclear ruthenium clusters molecular assembly and dynamics under redox state control

被引：3
作者：
Yoshimoto, Soichiro [1 ]
Kato, Jinnosuke [2 ]
Sakamoto, Hiroki [3 ]
Minamoto, Hironori [2 ]
Daicho, Keita [4 ]
Takamura, Kazuki [4 ]
Shimomoto, Naoki [4 ]
Abe, Masaaki [4 ]
机构：
[1] Kumamoto Univ, Inst Ind Nanomat, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan
[2] Kumamoto Univ, Grad Sch Sci & Technol, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan
[3] Kumamoto Univ, Dept Appl Chem & Biochem, Fac Engn, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan
[4] Univ Hyogo, Grad Sch Sci, 3-2-1 Koto, Kamigori, Hyogo 6781297, Japan
来源：
NANOSCALE | 2022年 / 14卷 / 25期
关键词：
DIRUTHENIUM COMPLEXES; ADLAYER; SURFACE;
D O I：
10.1039/d2nr01666d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mixed-valence ruthenium trinuclear clusters containing dichloroacetates were synthesized, and the self-assembly of a single molecular adlayer composed of these clusters on a graphite surface was investigated by atomic force microscopy (AFM). AFM clearly revealed the dynamics of two-dimensional (2D) structure formation as well as the molecular characteristics of the adlayers at different electrochemical interfaces. The results verified that the design of metal complexes is important not only for redox chemistry but also for molecular assembly and nanoarchitecture construction.
引用
收藏
页码：8929 / 8933
页数：5
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