Ultrathin Cu(In,Ga)Se2 based solar cells

被引:44
作者
Naghavi, N. [1 ,4 ]
Mollica, F. [2 ,4 ]
Goffard, J. [3 ,4 ]
Posada, J. [1 ,4 ]
Duchatelet, A. [2 ,4 ]
Jubault, M. [2 ,4 ]
Donsanti, F. [2 ,4 ]
Cattoni, A. [3 ,4 ]
Collin, S. [3 ,4 ]
Grand, P. P. [2 ,4 ]
Greffet, J. J. [5 ]
Lincot, D. [1 ,4 ]
机构
[1] CNRS, IRDEP, UMR 7174, 6 Quai Watier, F-78400 Chatou, France
[2] IRDEP, EDF R&D, 6 Quai Watier, F-78400 Chatou, France
[3] CNRS, LPN, Marcoussis, France
[4] Inst Photovolta Ile France, IPVF, 8 Rue Renaissance, F-92160 Antony, France
[5] CNRS, Inst Opt, Campus Polytech,RD 128, F-91127 Palaiseau, France
关键词
Ultrathin CIGS absorbers; Coevaporation; Reactive sputtering; Electrodeposition; Light management; Modelisation; THICKNESS; ABSORPTION; EFFICIENCY;
D O I
10.1016/j.tsf.2016.11.029
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The benefits of reducing the thickness of the Cu(In,Ga)Se-2 absorber (CIGS) in thin film solar cells outweighs the reduced material costs and production time. It also lowers the minimum quality requirements for the CIGS layer since shorter pathways for electron extraction allow shorter electron diffusion length. However, the design of ultrathin solar cells raises specific issues in terms of absorber quality, light management, and electronic transport. The aim of this paper is to give an overview of the state of the art on ultrathin CIGS solar cells and to present some results and perspectives for the improvement of the opto-electronic properties of ultra-thin solar cells. The impact of the deposition techniques for CIGS such as coevaporation, reactive sputtering and electrodeposition on the properties of ultrathin absorbers will be discussed. Then the potential of replacing the molybdenum back contact by a Transparent Conducting Oxide or a metallic or nanostructured reflectors will be analysed. (C) 2016 Published by Elsevier B.V.
引用
收藏
页码:55 / 60
页数:6
相关论文
共 22 条
[1]   Using radiative transfer equation to model absorption by thin Cu(In,Ga)Se2 solar cells with Lambertian back reflector [J].
Dahan, N. ;
Jehl, Z. ;
Guillemoles, J. F. ;
Lincot, D. ;
Naghavi, N. ;
Greffet, J. -J. .
OPTICS EXPRESS, 2013, 21 (03) :2563-2580
[2]   Optical approaches to improve the photocurrent generation in Cu(In,Ga)Se2 solar cells with absorber thicknesses down to 0.5 μm [J].
Dahan, N. ;
Jehl, Z. ;
Hildebrandt, T. ;
Greffet, J. -J. ;
Guillemoles, J. -F. ;
Lincot, D. ;
Naghavi, N. .
JOURNAL OF APPLIED PHYSICS, 2012, 112 (09)
[3]  
Goffard J., 2015, P 31 EUR PHOT SOL EN, P1050
[4]   In situ investigation of the formation of Cu(In,Ga)Se2 from selemsed metallic precursors by X-ray diffraction -: The impact of Gallium, Sodium and Selenium excess [J].
Hergert, F ;
Hock, R ;
Weber, A ;
Purwins, M ;
Palm, J ;
Probst, V .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2005, 66 (11) :1903-1907
[5]   Effects of heavy alkali elementsin Cu(In,Ga)Se2 solar cells with efficiencies up to 22.6% [J].
Jackson, Philip ;
Wuerz, Roland ;
Hariskos, Dimitrios ;
Lotter, Erwin ;
Witte, Wolfram ;
Powalla, Michael .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2016, 10 (08) :583-586
[6]   Investigating the electronic properties of Al2O3/Cu(In, Ga)Se2 interface [J].
Kotipalli, R. ;
Vermang, B. ;
Joel, J. ;
Rajkumar, R. ;
Edoff, M. ;
Flandre, D. .
AIP ADVANCES, 2015, 5 (10)
[7]   Towards ultrathin copper indium gallium diselenide solar cells: proof of concept study by chemical etching and gold back contact engineering [J].
Li-Kao, Zacharie Jehl ;
Naghavi, Negar ;
Erfurth, Felix ;
Guillemoles, Jean Francois ;
Gerard, Isabelle ;
Etcheberry, Arnaud ;
Pelouard, Jean Luc ;
Collin, Stephane ;
Voorwinden, Georg ;
Lincot, Daniel .
PROGRESS IN PHOTOVOLTAICS, 2012, 20 (05) :582-587
[8]   Influence of the Cu(In,Ga)Se2 thickness and Ga grading on solar cell performance [J].
Lundberg, O ;
Bodegård, M ;
Malmström, J ;
Stolt, L .
PROGRESS IN PHOTOVOLTAICS, 2003, 11 (02) :77-88
[9]   Time-resolved investigation of Cu(In,Ga)Se2 growth and Ga gradient formation during fast selenisation of metallic precursors [J].
Mainz, Roland ;
Weber, Alfons ;
Rodriguez-Alvarez, Humberto ;
Levcenko, Sergiu ;
Klaus, Manuela ;
Pistor, Paul ;
Klenk, Reiner ;
Schock, Hans-Werner .
PROGRESS IN PHOTOVOLTAICS, 2015, 23 (09) :1131-1143
[10]   Enhanced back reflectance and quantum efficiency in Cu(In,Ga)Se2 thin film solar cells with a ZrN back reflector [J].
Malmström, J ;
Schleussner, S ;
Stolt, L .
APPLIED PHYSICS LETTERS, 2004, 85 (13) :2634-2636