New Progress in Organic Synthesis through Organic Electron Transfer Chemistry

被引：2

作者：

Nishiguchi, Ikuzo ^{[1
]}

机构：

[1] Nagaoka Univ Technol, Dept Chem, Niigata 9402188, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2010年 / 68卷 / 08期

关键词：

organic synthesis; electron transfer; organic electrochemistry; Mg metal; radical ions; polar umpolung; high selectivity; particular behaviors; ELECTROORGANIC CHEMISTRY; CARBONYL-COMPOUNDS; ANODIC-OXIDATION; FACILE SYNTHESIS; C-ACYLATION; ELECTROREDUCTIVE ACYLATION; CYCLIZATION; ACYLLITHIUM; DERIVATIVES; SILYLATION;

D O I：

10.5059/yukigoseikyokaishi.68.824

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review consists of a number of highly selective and useful new organic synthetic reactions, which are characteristic with particular and selective reactivities and behaviors of radical ions intermediates, generated by transfer of one electron between organic molecule and electrodes, magnesium metal. Those reactions are also quite difficult or almost impossible to realize through usual carbocation, carbanion or radical intermediates, and may be classified as one of new fields, namely "Organic Synthesis by Organic Electron Transfer Chemistry".

引用

页码：824 / 833

页数：10

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