Synthesis of bio-based unsaturated polyester resins and their application in waterborne UV-curable coatings

被引：111
|
作者：
Dai, Jinyue [1 ,2 ]
Ma, Songqi [2 ]
Liu, Xiaoqing [2 ]
Han, Lijing [2 ]
Wu, Yonggang [1 ]
Dai, Xinyan [2 ]
Zhu, Jin [2 ]
机构：
[1] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo Key Lab Polymer Mat, Ningbo 315201, Zhejiang, Peoples R China
来源：
PROGRESS IN ORGANIC COATINGS | 2015年 / 78卷
关键词：
Bio-based; Unsaturated polyesters; Itaconic acid; Waterborne UV-curable coatings; FIRE RETARDANT POLYMERS; RENEWABLE RESOURCES; THERMAL-DEGRADATION; HIGH-PERFORMANCE; CROSS-LINKING; MECHANISM; INTUMESCENCE; METHACRYLATE; COMPOSITES; ISOSORBIDE;
D O I：
10.1016/j.porgcoat.2014.10.007
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
In this paper, three bio-based unsaturated polyesters were synthesized from itaconic acid and different diols which could be derived from renewable resources. Their chemical structures were confirmed by FT-IR, H-1 NMR and acid value as well as hydroxyl value. Waterborne UV curable networks based on these polyesters were manufactured and their mechanical properties, thermal stability and coating properties including pencil hardness, flexibility, adhesion, water resistance and solvent resistance were investigated. Results showed that the UV-cured polyester coatings exhibited high hardness, good water resistance and solvent resistance. The coatings reported in this paper combined the merits of bio-based materials, UV-curing process and water distribution. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：49 / 54
页数：6
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