Ruthenium nanoparticles supported on carbon oxide nanotubes for electrocatalytic hydrogen evolution in alkaline media

被引：8
作者：
Wang, Wei [1 ,2 ]
Yuan, Ting [1 ,2 ]
Tang, Hongting [1 ,2 ]
Hu, Zhizhi [3 ]
Wang, Yongfei [3 ,4 ]
Liu, Qinglei [1 ,2 ]
机构：
[1] Shanghai Inst Technol, Sch Perfume & Aroma Technol, 100 Haiquan Rd, Shanghai 201418, Peoples R China
[2] Minist Educ, Engn Res Ctr Perfume & Aroma & Cosmet, Shanghai 201418, Peoples R China
[3] Univ Sci & Technol Liaoning, Sch Chem Engn, 185 Qianshan Zhong Rd, Anshan 114044, Peoples R China
[4] Univ Sci & Technol Liaoning, Sch Met & Mat, 185 Qianshan Zhong Rd, Anshan 114044, Peoples R China
来源：
CHEMICAL PHYSICS LETTERS | 2021年 / 779卷
关键词：
Ruthenium nanoparticles; Oxide Nanotubes; Hydrogen evolution reaction; DOPED CARBON; RU NANOPARTICLES; FACILE SYNTHESIS; CATALYSTS; PH; EFFICIENT; GRAPHENE; OXYGEN; NANOCLUSTERS; INTERFACE;
D O I：
10.1016/j.cplett.2021.138879
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
"Cracking" water is of great significance to develop (HER) catalysts with high catalytic performance for nonplatinum hydrogen evolution under alkaline conditions. In this paper, we prepared a ruthenium nanoparticle catalyst on oxidized carbon nanotubes (Ru@OCNT) support. Electrochemical tests showed that Ru@OCNT-700 exhibited excellent catalytic performance and good stability under alkaline conditions (1 M KOH). When the current density reached 10 mA cm-2, it only needed an overpotential of 13.2 mV. The Tafel slope was 45.4 mV/ dec-1. Due to its excellent HER performance, Ru@OCNT electrocatalyst could have broad applicability in largescale hydrogen production.
引用
收藏
页数：7
相关论文
共 56 条
[1]   Facile synthesis of ultrafine Ru nanocrystal supported N-doped graphene as an exceptional hydrogen evolution electrocatalyst in both alkaline and acidic media [J].
Barman, Barun Kumar ;
Das, Debanjan ;
Nanda, Karuna Kar .
SUSTAINABLE ENERGY & FUELS, 2017, 1 (05) :1028-1033
[2]   Well-Defined Ru Nanoclusters Anchored on Carbon: Facile Synthesis and High Electrochemical Activity toward Alkaline Water Splitting [J].
Cheng, Xia ;
Wang, Hua ;
Ming, Mei ;
Luo, Wenxiu ;
Wang, Yi ;
Yang, Yingchun ;
Zhang, Yun ;
Gao, Daojiang ;
Bi, Jian ;
Fan, Guangyin .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (09) :11487-11492
[3]   Hydrogen Evolution Activity of Ruthenium Phosphides Encapsulated in Nitrogen- and Phosphorous-Codoped Hollow Carbon Nanospheres [J].
Chi, Jing-Qi ;
Gao, Wen-Kun ;
Lin, Jia-Hui ;
Dong, Bin ;
Yan, Kai-Li ;
Qin, Jun-Feng ;
Liu, Bin ;
Chai, Yong-Ming ;
Liu, Chen-Guang .
CHEMSUSCHEM, 2018, 11 (04) :743-752
[4]   Ruthenium Nanoparticles Supported on Carbon Microfibers for Hydrogen Evolution Electrocatalysis [J].
Creus, Jordi ;
Mallon, Laura ;
Romero, Nuria ;
Bofill, Roger ;
Moya, Alicia ;
Fierro, Jose L. G. ;
Mas-Balleste, Ruben ;
Sala, Xavier ;
Philippot, Karine ;
Garcia-Anton, Jordi .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (15) :2071-2077
[5]   Ligand-Capped Ru Nanoparticles as Efficient Electrocatalyst for the Hydrogen Evolution Reaction [J].
Creus, Jordi ;
Drouet, Samuel ;
Surinach, Santiago ;
Lecante, Pierre ;
Colliere, Vincent ;
Poteau, Romuald ;
Philippot, Karine ;
Garcia-Anton, Jordi ;
Sala, Xavier .
ACS CATALYSIS, 2018, 8 (12) :11094-11102
[6]   Electrocatalysts for Hydrogen Oxidation Reaction in Alkaline Electrolytes [J].
Davydova, Elena S. ;
Mukerjee, Sanjeev ;
Jaouen, Frederic ;
Dekel, Dario R. .
ACS CATALYSIS, 2018, 8 (07) :6665-6690
[7]   Reaction Pathways of Hydrogen-Evolving Electrocatalysts: Electrochemical and Spectroscopic Studies of Proton-Coupled Electron Transfer Processes [J].
Elgrishi, Noemie ;
McCarthy, Brian D. ;
Rountree, Eric S. ;
Dempsey, Jillian L. .
ACS CATALYSIS, 2016, 6 (06) :3644-3659
[8]   Ru nanodendrites composed of ultrathin fcc/hcp nanoblades for the hydrogen evolution reaction in alkaline solutions [J].
Gao, Kai ;
Wang, Yao ;
Wang, Zhiwei ;
Zhu, Zhaohua ;
Wang, Jialiang ;
Luo, Zhimin ;
Zhang, Cong ;
Huang, Xiao ;
Zhang, Hua ;
Huang, Wei .
CHEMICAL COMMUNICATIONS, 2018, 54 (36) :4613-4616
[9]   Periodic potentials in hybrid van der Waals heterostructures formed by supramolecular lattices on graphene [J].
Gobbi, Marco ;
Bonacchi, Sara ;
Lian, Jian X. ;
Liu, Yi ;
Wang, Xiao-Ye ;
Stoeckel, Marc-Antoine ;
Squillaci, Marco A. ;
D'Avino, Gabriele ;
Narita, Akimitsu ;
Muellen, Klaus ;
Feng, Xinliang ;
Olivier, Yoann ;
Beljonne, David ;
Samori, Paolo ;
Orgiu, Emanuele .
NATURE COMMUNICATIONS, 2017, 8
[10]   Cobalt Based Nanoparticles Embedded Reduced Graphene Oxide Aerogel for Hydrogen Evolution Electrocatalyst [J].
Koo, Sung Hwan ;
Li, Dong Jun ;
Yun, Taeyeong ;
Choi, Dong Sung ;
Lee, Kyung Eun ;
Lee, Gil Yong ;
Oh, Youngtak ;
Lim, Joonwon ;
Sasikala, Suchithra Padmajan ;
Lee, Ho Jin ;
Kim, In Ho ;
Jung, Hong Ju ;
Jain, Rishabh ;
Kim, Sang Ouk .
PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, 2019, 36 (07)
123456