Polymerization of 6-amino-6-deoxy-D-glucose involving amadori rearrangement: A new method for synthesis of aminopolysaccharide

被引：4

作者：

Kadokawa, J ^{[1
]}

Hino, D ^{[1
]}

Karasu, M ^{[1
]}

Tagaya, H ^{[1
]}

Chiba, K ^{[1
]}

机构：

[1] Yamagata Univ, Fac Engn, Dept Mat Sci & Engn, Yonezawa, Yamagata 9920038, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 05期

关键词：

D O I：

10.1246/cl.1998.383

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes synthesis of a new aminopolysaccharide by thermal polymerization of 6-amino-6-deoxy-D-glucose in the presence of acetic acid. The polymerization proceeded via Amadori rearrangement to give the aminopolysaccharide having aminoketose structure in the main chain. The molecular weight was determined by GPC analysis after acetylation of the product polysaccharide.

引用

页码：383 / 384

页数：2

共 50 条

[21] AMADORI COMPOUNDS FROM MONOMETHYLGLUCOSES - A PRACTICAL SYNTHESIS OF 6-O-METHYL-D-GLUCOSE
VANCLEVE, JW
INGLETT, GE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 187 (APR): : 49 - CARB
[22] Large-scale synthesis and radiolabelling of 6-deoxy-6-iodo-D-glucose (6-DIG)
Charronneau, E
Mathieu, JP
Morin, C
APPLIED RADIATION AND ISOTOPES, 1998, 49 (12) : 1605 - 1607
[23] SYNTHESIS AND NMR-SPECTROSCOPY OF DERIVATIVES OF 6-AMINO-6-DEOXY-D-GALACTOSE-6-N-15
COXON, B
REYNOLDS, RC
CARBOHYDRATE RESEARCH, 1980, 78 (01) : 1 - 16
[24] BIOCHEMICAL STUDIES ON THIOSUGARS .3. SYNTHESIS OF 6-DEOXY-6-MERCAPTO-D-GLUCOSE
AKAGI, M
HAGA, M
TEJIMA, S
CHEMICAL & PHARMACEUTICAL BULLETIN, 1962, 10 (07) : 562 - +
[25] SOME DERIVATIVES OF 6-AMINO-6-DEOXY-D-GLUCONIC ACID THAT ARE PRECURSORS FOR THE SYNTHESIS OF POLYAMIDES
MARTINEZ, MB
MATA, FZ
DONOSO, MTU
PEREZ, JAG
CARBOHYDRATE RESEARCH, 1992, 230 (01) : 191 - 195
[26] CHEMISTRY OF GLYCOSYLPHOSPHATES AND THEIR DERIVATIVES .2. SYNTHESIS OF DEOXYGLYCOSYLPHOSPHATES, DERIVATIVES OF 6-DEOXY-D-GLUCOSE, 4-DEOXY-D-GLUCOSE AND 3-DEOXY-D-GLUCOSE
SHIBAEV, VN
KUSOV, YY
KUCHAR, S
KOCHETKO.NK
IZVESTIYA AKADEMII NAUK SSSR-SERIYA KHIMICHESKAYA, 1973, (02): : 430 - 434
[27] NEW SYNTHESIS OF D-RHAMNOSE (6-DEOXY-D-MANNOSE)
ZORBACH, WW
TIO, CO
JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (09): : 3543 - &
[28] AMINO SUGARS .70. SYNTHESIS OF 2-ACETAMIDO-2-DEOXY-6-O-ALPHA-D-MANNOPYRANOSYL-D-GLUCOSE
SHABAN, M
JEANLOZ, RW
CARBOHYDRATE RESEARCH, 1971, 17 (02) : 411 - &
[29] SYNTHESIS AND BIOLOGICAL-ACTIVITIES OF 2-AMINO-2-DEOXY AND 6-AMINO-6-DEOXY-ALPHA-D-GLUCOPYRANOSYL-2,5-DIDEOXYSTREPTAMINES
OGAWA, S
FUNAKI, Y
IWATA, K
SUAMI, T
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1976, 49 (07) : 1975 - 1979
[30] SYNTHESIS OF SOME DERIVATIVES OF 6-AMINO-1,5-ANHYDRO-6-DEOXY-D-GLUCITOL AND 2-AMINO-1,5-ANHYDRO-2-DEOXY-D-GLUCITOL
WITCZAK, ZJ
WHISTLER, RL
CARBOHYDRATE RESEARCH, 1986, 150 (01) : 121 - 131

← 1 2 3 4 5 →