Polymerization of 6-amino-6-deoxy-D-glucose involving amadori rearrangement: A new method for synthesis of aminopolysaccharide

被引：4

作者：

Kadokawa, J ^{[1
]}

Hino, D ^{[1
]}

Karasu, M ^{[1
]}

Tagaya, H ^{[1
]}

Chiba, K ^{[1
]}

机构：

[1] Yamagata Univ, Fac Engn, Dept Mat Sci & Engn, Yonezawa, Yamagata 9920038, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 05期

关键词：

D O I：

10.1246/cl.1998.383

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes synthesis of a new aminopolysaccharide by thermal polymerization of 6-amino-6-deoxy-D-glucose in the presence of acetic acid. The polymerization proceeded via Amadori rearrangement to give the aminopolysaccharide having aminoketose structure in the main chain. The molecular weight was determined by GPC analysis after acetylation of the product polysaccharide.

引用

页码：383 / 384

页数：2

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