Developing Y-Branched Polymer Acceptor with 3D Architecture to Reconcile Between Crystallinity and Miscibility Yielding >15% Efficient All-Polymer Solar Cells

In all-polymer solar cells (all-PSCs), there remains such a dilemma that obtains good miscibility and crystallinity simultaneously. Herein a new family of Y-shape polymer acceptor, namely PYTT is developed, which is copolymerized from Y6 and benzotrithiophene units in three-way directions. Benefiting from its high-density end-chains and extended pi-conjugation thanks to highly-branched 3D architecture, PYTT displays better organic solubility despite much higher molecular weights, larger crystallinity, and tighter pi-stacking than the linear counterpart-PYT comprising Y6 and thiophene moieties, while showing identical optical absorption yet threefold higher photoluminescence intensity. In PYTT blend film with PM6 polymer donor, the interpenetrating nano-fibrillar structures are formed with well-intermixed polymeric domain sizes close to the exciton diffusion length, which is greatly conducive to exciton dissociation and charge transport in device. Consequently, PYTT-based all-PSCs exhibit all increased photovoltaic parameters, yielding a decent power conversion efficiency of 15.60%, which is approximate to 20% enhancement over PYT-based device, along with low nonradiative loss of 0.221 meV.