Luminescence characteristics and X-ray crystal structure of [Cd(bipy)3][PF6]2 (bipy=2,2′-bipyridine)

被引：15
|
作者：
Kundu, N
Mandal, D
Chaudhury, M [1 ]
Tiekink, ERT
机构：
[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, W Bengal, India
[2] Griffith Univ, Sch Sci, Brisbane, Qld 4111, Australia
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2005年 / 19卷 / 12期
关键词：
cadmium(II); 2,2 '-bipyridine; luminescence; crystal structure;
D O I：
10.1002/aoc.996
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The photoluminescence characteristics of the [Cd(biPY)(3)][PF6](2) complex are reported. A moderately large quantum yield (phi) of 1.07 x 10(-2) is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by C-H-. . . pi and C-H-. . . F interactions. Copyright (c) 2005 John Wiley & Sons, Ltd.
引用
收藏
页码：1268 / 1270
页数：3
相关论文
共 50 条
  • [1] Crystal structure of [Co(bipy)(maleato) (H2O)3]·H2O (bipy = 2,2′-bipyridine)
    Cun-Gen Zhang
    Yong-Jun Leng
    Zi-Feng Ma
    De-Yue Yan
    Journal of Chemical Crystallography, 1999, 29 : 1081 - 1084
  • [2] Crystal structure of [Co(bipy)(maleato) (H2O)3]•H2O (bipy=2,2′-bipyridine)
    Zhang, CG
    Leng, YJ
    Ma, ZF
    Yan, DY
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1999, 29 (10) : 1081 - 1084
  • [3] A novel tetranuclear iron complex [Fe4O2(O2CC2H5)7(bipy)2]PF6•2H2O (bipy=2,2′-bipyridine):: Synthesis, crystal structure and magnetic properties
    Yan, B
    Chen, ZD
    POLISH JOURNAL OF CHEMISTRY, 2001, 75 (06) : 785 - 793
  • [4] A novel tetranuclear iron complex [Fe4O2(O2CC2H5)7(bipy)2]PF6•2H2O (bipy=2, 2′-bipyridine):: crystal structure and magnetic property
    Yan, B
    Chen, ZD
    INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (03) : 138 - 141
  • [5] Crystal Structure, and Magnetic and Fluorescence Properties of a New Terbium(III) Complex, [Tb(L)3(2,2′-bipy)(DMF)]•(2,2′-bipy)
    Yang, Ying-Qun
    Zhang, Shao-Hua
    Tan, Hong-Bo
    Fu, Li-Xia
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (11): : 1269 - 1272
  • [6] Crystal　Structure　and　Luminescence　Spectra　of　Ternary　Europium(Ⅲ)　Complex［Eu(DBM)3(2，2＇－BIPY)］(HDBM)
    王明昭
    金林培
    蔡冠梁
    刘世雄
    黄金陵
    秦伟平
    黄世华
    JOURNAL OF RARE EARTHS, 1994, (03) : 166 - 169
  • [7] Crystal structure of the coordination compound of triiodidomethyltin(IV) with 2,2 '-bipyridine, MeSnI3 center dot bipy
    Reuter, Hans
    Reichelt, Martin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 17 - +
  • [8] Synthesis and crystal and molecular structure of mixed-ligand complexes Cd(2,2′-Bipy)(i-PrOCS2)2 and(2,2′-Bipy)(i-BuOCS2)2
    Larionov, S. V.
    Glinskaya, L. A.
    Leonova, T. G.
    Klevtsova, R. F.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (06) : 1023 - 1030
  • [9] Synthesis and crystal and molecular structure of mixed-ligand complexes Cd(2,2′-Bipy)(i-PrOCS2)2 and (2,2′-Bipy)(i-BuOCS2)2
    S. V. Larionov
    L. A. Glinskaya
    T. G. Leonova
    R. F. Klevtsova
    Journal of Structural Chemistry, 2005, 46 : 1023 - 1030
  • [10] The crystal structure of [La(NO3)6{Cu(2,2′-bipy)2}2][La(NO3)6Cu(2,2′-bipy)2]•CH3CN with the most profuse modes of nitrate coordination
    Jianmin, L
    Huaqianga, Z
    Yugen, Z
    Jinhua, C
    Yanxiong, K
    Quanming, W
    Xintao, W
    CRYSTAL RESEARCH AND TECHNOLOGY, 1999, 34 (07) : 925 - 928
12345