Room-Temperature C-H Arylation: Merger of Pd-Catalyzed C-H Functionalization and Visible-Light Photocatalysis

被引：575

作者：

Kalyani, Dipannita ^{[1
]}

McMurtrey, Kate B. ^{[1
]}

Neufeldt, Sharon R. ^{[1
]}

Sanford, Melanie S. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 46期

关键词：

ARYL BOND FORMATION; COUPLING REACTIONS; PSCHORR REACTION; DIAZONIUM SALTS; PHOTO-OXIDATION; PALLADIUM; ACTIVATION; COMPLEXES; SYSTEM; SERIES;

D O I：

10.1021/ja208068w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication describes the development of a room-temperature ligand-directed C-H arylation reaction using aryldiazonium salts. This was achieved by the successful merger of palladium-catalyzed C-H functionalization and visible-light photoredox catalysis. The new method is general for a variety of directing groups and tolerates many common functional groups.

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收藏

页码：18566 / 18569

页数：4

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