Two-step Changes in Luminescence Color of Pt(II) Complex Bearing an Amide Moiety by Mechano- and Vapochromism

被引:74
作者
Choi, Seong Jib [1 ,2 ]
Kuwabara, Junpei [1 ,2 ]
Nishimura, Yoshinobu [1 ,3 ]
Arai, Tatsuo [1 ,3 ]
Kanbara, Takaki [1 ,2 ]
机构
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba Res Ctr Interdisciplinary Mat Sci TIMS, Tsukuba, Ibaraki 3058573, Japan
[2] Univ Tsukuba, Grad Sch Pure & Appl Sci, Dept Mat Sci, Tsukuba, Ibaraki 3058573, Japan
[3] Univ Tsukuba, Grad Sch Pure & Appl Sci, Dept Chem, Tsukuba, Ibaraki 3058573, Japan
关键词
CYCLOMETALATED PLATINUM(II) COMPLEXES; PI-PI INTERACTIONS; ELECTROLUMINESCENT DEVICES; MODULATION; EMISSION;
D O I
10.1246/cl.2012.65
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A pincer Pt(II) complex with amide groups was investigated with respect to the change in their luminescence color in solid state. The Pt(II) complex exhibited mechanochromic behavior, changing from green to orange upon grinding. In addition, the orange luminescence changed to yellow via vapochromism.
引用
收藏
页码:65 / 67
页数:3
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