Poly(anthraquinonyl sulfide) cathode for potassium-ion batteries

被引:225
作者
Jian, Zelang [1 ]
Liang, Yanliang [2 ,3 ]
Rodriguez-Perez, Ismael A. [1 ]
Yao, Yan [2 ,3 ,4 ]
Ji, Xiulei [1 ]
机构
[1] Oregon State Univ, Dept Chem, Gilbert Hall 153, Corvallis, OR 97331 USA
[2] Univ Houston, Dept Elect & Comp Engn, Houston, TX 77204 USA
[3] Univ Houston, Mat Sci & Engn Program, Houston, TX 77204 USA
[4] Univ Houston, Texas Ctr Superconduct, Houston, TX 77204 USA
基金
美国国家科学基金会;
关键词
Potassium-ion batteries; Organic material; Cathode; Polymer; SODIUM; ELECTRODES; INTERCALATION; GRAPHITE;
D O I
10.1016/j.elecom.2016.07.011
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Potassium-ion batteries (KIBs) are a promising sustainable energy storage technology due to the high abundance and low cost of potassium. Carbon anode materials for KIBs have seen great successes, but the development of cathode materials is yet to catch up. In this study, poly(anthraquinonyl sulfide) (PAQS) is evaluated as a cathode material for KIBs. It exhibits a high reversible capacity of 200 mAh/g, which is the highest value for a potassium storage cathode material. The cell shows two slopes averaged at 2.1 and 1.6 V vs. K+/K. It shows a good cycling performance with the capacity retention of 75% after 50 cycles at a rate of C/10. These preliminary results indicate that PAQS is a promising cathode material for KIBs. (C) 2016 Published by Elsevier B.V.
引用
收藏
页码:5 / 8
页数:4
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